等离子体表面处理改善超高分子量聚乙烯纤维表面粘接性能
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IMPROVING ULTRA-HIGH MOLECULAR WEIGHT POLYETHYENE(UHMW-PE)FIBRE SURFACE ADHESION BY PLASMA TREATMENT
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    摘要:

    超高分子量聚乙烯纤维(UHMW-PE)由于结构特性导致其粘接性很差,给高性能轻型复合材料的研制带来困难。本实验采用低温等离子体以及铬酸等对各种拉伸比的UHMW-PE纤维进行表面改性,通过纤维拔出环氧树脂基体测界面粘接强度,利用SEM观察研究了界面脱粘机理。结果表明:经等离子体处理后。界面粘接强度可提高四倍以上,其大小与纤维拉伸比及等离子体处理参数均有关;界面产生的裂纹在纤维内部沿纤维方向扩展,拔出后纤维表面层被剥掉;等离子体处理方法与化学表面处理方法相结合。可望进一步提高界面粘接强度。

    Abstract:

    It's very difficult to study high-strenth compositesbecause of the poor adhesion of polyethylene fibres caused by its specialstructural qualities.This paper reports a study of changing the surfacequalities of ultra high molecular weight polyethyene(UHMW-PE)fibres of different draw ratios by plasma and acid treatment.It alsodevotes to the experiments of measuring the fibre resin adhesion bythe pull out technigue,and studies the mechanism of the interface failureby SEM.The experimental results show that there's a significant impr-ovement in the adhesion between the UHMW-PE fibres and the resinafter the plasma treatment and it can be four times stronger,dependingupon the draw ratios of fibres and plasma parameters,The interfacefailure in the pull-out test involved developes along the fibre-resininterface within the fibre,and the skin of the fibre is peeled off.Theadhesion can be improved by combining the plasma etching technique andother methods of treating the surface of UHMW-PE fibre.

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高尚林,牟其伍,袁超廷.等离子体表面处理改善超高分子量聚乙烯纤维表面粘接性能[J].土木与环境工程学报(中英文),1992,14(2). Gao Shanglin Testing CentreMou Qiwu, Yuan Chaoting Dept. of Natural Science. IMPROVING ULTRA-HIGH MOLECULAR WEIGHT POLYETHYENE(UHMW-PE)FIBRE SURFACE ADHESION BY PLASMA TREATMENT[J]. JOURNAL OF CIVIL AND ENVIRONMENTAL ENGINEERING,1992,14(2).10.11835/j. issn.1674-4764.1992.02.008

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