碳化作用对固化铅污染土强度特性和微观结构的影响
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作者:
作者单位:

1.黄河勘测规划设计研究院有限公司,郑州 450003;2.水利部黄河流域水治理与水安全重点实验室(筹),郑州 450003;3.东南大学 交通学院,南京 211189

作者简介:

仝亮(1979- ),男,正高级工程师,主要从事水利工程研究,E-mail:tongliang_yrec@126.com。
TONG Liang (1979- ), PhD, senior engineer, main research interest: water conservancy project, E-mail: tongliang_yrec@126.com.

通讯作者:

曹智国(通信作者),男,博士,E-mail:caozhgyrec@163.com。

中图分类号:

TU411

基金项目:

国家自然科学基金(51578148);水利重大关键技术研究项目(2021KY04(S))


Effects of carbonation on strength and microstructure of cement-solidified lead-contaminated soils
Author:
Affiliation:

1.Yellow River Engineering Consulting Co., Ltd., Zhengzhou450003, P. R. China;2.Key Laboratory of Water Management and Water Security for Yellow River Basin, Ministry of Water Resources (under construction), Zhengzhou450003, P. R. China;3.School of Transportation, Southeast University, Nanjing211189, P. R. China

Fund Project:

National Natural Science Foundation of China (No. 51578148); Key Technology Research Project of the Ministry of Water Resources (No. 2021KY04(S))

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    摘要:

    碳化作用是影响水泥固化重金属污染土耐久性的一个重要因素,为探明长期服役过程中碳化作用下固化污染土强度特性的演化规律,人工配制铅污染土,采用水泥固化处理后进行碳化试验,分析碳化作用和压实度对固化土无侧限抗压强度的影响规律,并通过扫描电镜和压汞试验分析碳化作用对微观矿物形态和微观孔隙结构的影响。结果表明:碳化作用下固化铅污染土的无侧限抗压强度降低,15%水泥掺入量的固化土强度降低44%~45%,这是碳化反应产物填充效应增强和土颗粒间胶结作用减弱共同作用的结果;固化土强度与孔隙率具有很好的幂函数关系,揭示了填充作用对固化土强度的影响;碳化作用下固化铅污染土中观察到较多结晶状态良好的碳化反应产物CaCO3,固化土总的孔隙体积减小,小于0.01 μm的凝胶孔和0.01~0.1 μm的小毛细孔所占比例减少,0.1~10 μm的大毛细孔和大于10 μm的大孔隙所占比例增加。

    Abstract:

    Carbonation is an important factor affecting the durability of cement-solidified heavy metal-contaminated soils. In order to explore the influence of carbonation on the strength of solidified contaminated soils, lead-contaminated soils were artificially prepared, and carbonation tests were carried out after cement solidification treatment. The effects of carbonation and compactness on unconfined compressive strength(UCS) of solidified soils were analyzed, and the effects of carbonation on micro mineral morphology and micro pore structure were also analyzed by electron microscope scanning and mercury injection tests. The test results show that UCS of solidified lead-contaminated soils decreases under carbonation, the strength of solidified soils with 15% cement content is reduced by 44%-45%, which is the result of the filling enhancement effect of carbonation reaction products and the weakening of cementation between soil particles. There is a good power function relationship between UCS and porosity of solidified soils, which reveals the influence of filling on strength of solidified soils. Under carbonation, crystalline carbonation reaction product CaCO3 is observed, the total pore volume of solidified soils decreases, the proportion of gel pores less than 0.01 μm and capillary pores between 0.01 μm and 0.1 μm decreases, and the proportion of capillary pores between 0.1 μm and 10 μm and macro pores greater than 10 μm increases.

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仝亮,曹智国,杨风威.碳化作用对固化铅污染土强度特性和微观结构的影响[J].土木与环境工程学报(中英文),2024,46(6):16-22. TONG Liang, CAO Zhiguo, YANG Fengwei. Effects of carbonation on strength and microstructure of cement-solidified lead-contaminated soils[J]. JOURNAL OF CIVIL AND ENVIRONMENTAL ENGINEERING,2024,46(6):16-22.10.11835/j. issn.2096-6717.2022.089

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  • 收稿日期:2022-04-18
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  • 在线发布日期: 2024-11-27
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