流态固化淤泥复合胶凝材料配比优化及其固化机理
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作者:
作者单位:

1.重庆大学 土木工程学院,重庆 400045;2.中宝检测技术(重庆)有限公司,重庆401120;3.上海市政工程设计研究总院(集团)有限公司,上海 200092

作者简介:

林文逸(2000- ),男,主要从事流态固化土研究,E-mail:1162564316@qq.com。
LIN Wenyi (2000- ), main research interest: fluidized solidified soil, E-mail: 1162564316@qq.com.

通讯作者:

方祥位(通信作者),男,博士,教授,博士生导师,E-mail:fangxiangwei1975@163.com。

中图分类号:

TU472.5

基金项目:

重庆英才创新创业示范团队项目(cstc2024ycjh-bgzxm0012);中央高校基本科研业务费(2023CDJKYJH105);重庆市建设科技计划(城科字2024第2-2号);上海市政工程设计研究总院(集团)有限公司科学研究项目(K2023K124A)


Ratio optimization and solidification mechanism of composite cementing materials of fluidized solidified sludge
Author:
Affiliation:

1.School of Civil Engineering, Chongqing University, Chongqing 400045, P. R. China;2.Zhongbao Testing Technology (Chongqing) Co., Ltd., Chongqing 401120, P. R. China;3.Shanghai Municipal Engineering Design Institute (Group) Co., Ltd., Shanghai 200092, P. R. China

Fund Project:

Chongqing Talent Innovation and Entrepreneurship Demonstration Team Projects (No. cstc2024ycjh-bgzxm0012); The Fundamental Research Funds for the Central Universities (No. 2023CDJKYJH105); Chongqing Construction Science and Technology Plan Project (No. City Science-2024-2-2); Scientific Research Project of Shanghai Municipal Engineering Design Institute (Group) Co., Ltd. (No. K2023K124A)

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    摘要:

    流态固化土具有高流动性、自密实、强度可控等特点,可解决回填场地狭小、回填空间狭窄等填筑工程难题,其流态固化材料主要包括胶凝组分和流动组分,目前针对淤泥的流态固化胶凝材料和固化机理研究尚不充分。采用矿粉和水泥作为基础胶凝材料,通过单因素试验确定激发剂(生石灰和硅酸钠)的适宜掺量,借助Design Expert软件进行响应面分析,得到复合胶凝材料的优化配比;通过XRD和SEM试验得到固化淤泥的产物种类和微观结构,分析复合胶凝材料的固化机理。结果表明,复合胶凝材料(CCM)中水泥∶矿粉∶生石灰∶硅酸钠的优化配比为38∶42∶9.7∶6.5,采用CCM的流态固化淤泥的流动度和强度均优于仅采用水泥的流态固化淤泥。CCM固化淤泥的水化产物主要包括水化硅酸钙凝胶和钙矾石,水化产物包裹土颗粒并填充孔隙,显著提高了流态固化淤泥的强度。CCM的固化淤泥强度提高包括水化作用、碱激发火山灰反应、离子交换作用、微膨胀和填充作用等。

    Abstract:

    Fluidized solidified soil, due to its high fluidity, self-compaction, and controllable strength, can solve filling engineering problems such as narrow backfill sites and narrow backfill spaces, and fluidized solidified materials mainly include cementitious components and flow components. Using slag and cement as basic cementitious materials, the appropriate dosage of the activators (quicklime and sodium silicate) were determined through single factor tests. Response surface analysis was conducted using Design Expert software to obtain the optimized ratio of composite cementitious materials. The types and microstructure of solidified sludge products were obtained through XRD and SEM experiments, and the solidification mechanism of composite cementitious materials was analyzed. The results showed that the optimized ratio of composite cementitious material (CCM) cement∶slay∶quicklime∶sodium silicate was 38∶42∶9.7∶6.5. The fluidity and strength of the fluidized solidified sludge using CCM were better than those using only cement. The hydration products of CCM solidified sludge mainly include hydrated calcium silicate gel and ettringite. The hydration products encapsulate soil particles and fill pores, significantly improving the strength of fulidized solidified sludge. The strength improvement of CCM solidified sludge includes hydration, alkali induced pozzolanic reaction, ion exchange, micro expansion and filling effects.

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林文逸,方祥位,雷运涛,黄晟,江文琛.流态固化淤泥复合胶凝材料配比优化及其固化机理[J].土木与环境工程学报(中英文),2026,48(2):100-110. LIN Wenyi, FANG Xiangwei, LEI Yuntao, HUANG Sheng, JIANG Wenchen. Ratio optimization and solidification mechanism of composite cementing materials of fluidized solidified sludge[J]. JOURNAL OF CIVIL AND ENVIRONMENTAL ENGINEERING,2026,48(2):100-110.10.11835/j. issn.2096-6717.2024.089

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  • 收稿日期:2024-06-24
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  • 在线发布日期: 2026-03-31
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