MICP协同氧化镁固化Zn2+污染红黏土的效果试验研究
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作者单位:

桂林理工大学 土木工程学院;广西岩土力学与工程重点实验室, 广西 桂林 541004

作者简介:

宋宇(1981- ),女,博士,副教授,主要从事微生物岩土研究,E-mail:songyu119@glut.edu.cn。
SONG Yu (1981- ), PhD, associate professor, main research interest: microbial geotechnics, E-mail: songyu119@glut.edu.cn.

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中图分类号:

TU411.3

基金项目:

国家自然科学基金(42262030);广西岩溶动力学重大科技创新基地开放课题(KDL & Guangxi202303);河南省科技研发计划联合基金(225200810005);广西岩土力学与工程重点实验室开放课题(桂科岩2023-XT-02)


Effect of MICP synergized with magnesium oxide on solidification of Zn2+ contaminated red clay
Author:
Affiliation:

School of Civil Engineering;Guangxi Key Laboratory of Geomechanics and Geotechnical Engineering, Guilin University of Technology, Guilin 541004, Guangxi, P. R. China

Fund Project:

National Natural Science Foundation of China (No. 42262030); Guangxi Key Science and Technology Innovation Base on Karst Dynamics (No. KDL&Guangxi202303); Henan Science and Technology R & D Program Joint Fund (No. 225200810005); Open Subjects of Guangxi Key Laboratory of Geotechnical Mechanics and Engineering (No. 2023-XT-02)

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    摘要:

    随着工业化进程的加快,Zn2?的污染问题日益严重,对生态系统和工程结构的稳定性构成重大威胁。为了应对这一挑战,研究MICP(microbially induced carbonate precipitation)协同氧化镁技术对Zn2?污染红黏土的固化效果。采用无侧限抗压强度试验和直接剪切试验,探讨在不同胶结液浓度、氧化镁掺量及Zn2+浓度下固化土的无侧限抗压强度及抗剪强度指标变化规律;通过离子赋存形态试验,结合固化前后试样pH值的变化情况,分析MICP协同氧化镁技术对Zn2?的固化效果。结果表明:氧化镁的掺入显著提高了Zn2?污染红黏土的无侧限抗压强度和抗剪强度,当氧化镁掺量为5%时,利用率最高;胶结液浓度为1.0 mol/L时,抗压强度和抗剪强度最高;固化试样的抗剪强度指标主要受氧化镁掺量的影响;氧化镁的掺入能够提高土壤的pH值,进而促进MICP过程中碳酸钙的沉淀,加速Zn2?从弱酸提取态向可还原态、可氧化态和残渣态转化。

    Abstract:

    As industrialization accelerates, the pollution problem of Zn2+ is becoming increasingly severe, posing a significant threat to the stability of ecosystems and engineering structures. To cope with this challenge, this study examines the solidification effect of MICP (Microbially Induced Carbonate Precipitation) synergized with magnesium oxide on Zn2+ contaminated red clay. The variation of unconfined compressive strength (UCS) and shear strength index of solidified soil under different concentrations of cementation solution, magnesium oxide contents and Zn2+ concentrations were investigated by UCS tests and direct shear tests. The curing effect of MICP synergized with magnesium oxide technology on Zn2+ was analyzed by ion occurrence form test and pH value changes of samples before and after curing. The results show that the incorporation of magnesium oxide significantly improves the UCS and shear strength of Zn2+ contaminated red clay. When the content of magnesium oxide is 5%, the utilization rate is the highest. When the concentration of cementation solution is 1.0 mol/L, the UCS and shear strength are the highest. The shear strength index of solidified samples is mainly affected by the content of magnesium oxide. The incorporation of magnesium oxide facilitates calcium carbonate precipitation during MICP by increasing the pH value. This process accelerates the transformation of zinc ions from a weak acid-extractable state to reducible, oxidizable, and residual states.

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宋宇,成继春,陈玉玲,李嘉琦,刘伟.MICP协同氧化镁固化Zn2+污染红黏土的效果试验研究[J].土木与环境工程学报(中英文),2026,48(3):30-40. SONG Yu, CHENG Jichun, CHEN Yuling, LI Jiaqi, LIU Wei. Effect of MICP synergized with magnesium oxide on solidification of Zn2+ contaminated red clay[J]. JOURNAL OF CIVIL AND ENVIRONMENTAL ENGINEERING,2026,48(3):30-40.10.11835/j. issn.2096-6717.2024.078

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  • 收稿日期:2024-06-17
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  • 在线发布日期: 2026-06-10
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