石墨烯增强传统砂岩文物修复材料性能研究
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作者单位:

1.中铁西北科学研究院有限公司;2.兰州大学土木工程与力学学院;3.乐山大佛风景名胜区管理委员会

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中图分类号:

TU521

基金项目:

四川省科技计划项目(2020YFS0391);中国中铁科学研究院有限公司重点课题(2019-KJ011-Z010-A2,2020-KJ009-Z009-A2)。


Enhanced Mechanical Properties with Graphene in the Traditional Sandstone Cultural Relics Mortar for Conservation
Author:
Affiliation:

1.Northwest Research Institute Co. Ltd. of C.R.E.C.;2.School of Civil Engineering and Mechanics,Lanzhou University;3.Leshan Giant Buddha Management Committee

Fund Project:

Sichuan Science and Technology Program (No. 2020YFS0391); Key Research Project of China Railway Academy Co. Ltd. (No. 2019-KJ011-Z010-A2, No. 2020-KJ009-Z009-A2).

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    摘要:

    川渝地区分布有8000余处石窟和摩崖造像,大部分凿刻于砂岩中,长期环境作用导致砂岩性能劣化,对赋存文化遗产的安全造成威胁。为了提升传统砂岩文物修复材料的性能,将石墨烯纳米片加入传统修复材料中,运用传统工艺制备出“CH@G”灰浆。研究结果表明,加入石墨烯纳米片的CH@G灰浆,其力学性能和体积稳定性较传统材料明显提高。当石墨烯纳米片的添加量为0.07wt%时,样品力学性能最佳,56d抗压强度、抗折强度和抗拉强度分别为4.21MPa、2.21MPa和0.47MPa,相对于传统修复材料,强度分别提升了7.36%、19.46%和51.61%。FT-IR、Raman和XRD结果表明,石墨烯纳米片对固化反应产物影响较小,并且可以在早期加速水化反应,从而提升早期强度。SEM结果表明,石墨烯纳米片作为一种调节相,促使灰浆形成均匀致密的微观结构。

    Abstract:

    More than 8000 grottoes and cliff statues located in Sichuan and Chongqing areas, and most of them are made from sandstone. The properties of sandstone are deteriorated due to long-term environmental effects, which pose threats to the cultural relics. Graphene sheets are added to the traditional sandstone cultural relics mortarto enhance the properties, which is defined as “CH@G mortars”. The mechanical properties and volume stability of CH@G mortars are enhanced by Graphene sheets. The specimen with the highest strength is obtained by addition of 0.07 wt% Graphene sheets,and its values (increase proportion compared with CH mortar) of compressive strength, flexural strength and tensile strength at 56 days are 4.21 MPa (7.36 %), 2.21 MPa (19.46 %) and 0.47 MPa (51.61 %), respectively. The results of FT-IR and Raman spectra show that Graphene sheets have little influence on the composition of products, and Graphene sheets could accelerate the hydration in early age according to the XRD results. SEM images exhibit that Graphene sheets could act as a regulate phase to form uniform and compacted microstructure.

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  • 收稿日期:2020-04-07
  • 最后修改日期:2020-08-10
  • 录用日期:2020-08-16
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