碳化作用对固化铅污染土强度特性和微观结构的影响
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作者单位:

1. 黄河勘测规划设计研究院有限公司;2. 水利部黄河流域水治理与水安全重点实验室(筹);3. 东南大学

作者简介:

曹智国(1990-),男,河南三门峡人,博士,主要从事特殊土处理和隧道工程等方面的研究。E-mail:caozhgyrec@163.com

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中图分类号:

TU41

基金项目:

国家自然科学基金项目(面上项目),水利重大关键技术研究项目


Effects of carbonation on strength and microstructure of cement-solidified lead-contaminated soils
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Affiliation:

1. Yellow River Engineering Consulting Co., Ltd.;2. Key Laboratory of Water Management and Water Security for Yellow River Basin, Ministry of Water Resources (under construction);3. Southeast University

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    摘要:

    碳化作用是影响水泥固化重金属污染土耐久性的一个重要因素。为探明长期服役过程中碳化作用下固化污染土强度特性的演化规律,人工配制铅污染土,采用水泥固化处理后进行碳化试验,分析碳化作用和压实度对固化土无侧限抗压强度的影响规律,并通过扫描电镜和压汞试验,分析碳化作用对微观矿物形态和微观孔隙结构的影响。试验结果表明,碳化作用下固化铅污染土的无侧限抗压强度降低,15 %水泥掺入量的固化土强度降低44 % ~ 45 %,这是由碳化反应产物填充增强效应和土颗粒间胶结作用减弱共同作用的结果。固化土强度与孔隙率具有很好的幂函数关系,揭示了填充作用对固化土强度的影响。碳化作用下固化铅污染土中观察到较多的结晶状态良好的碳化反应产物CaCO3,固化土总的孔隙体积减小,< 0.01 μm的凝胶孔和0.01 μm ~ 0.1 μm的小毛细孔所占的比例减少,0.1 μm ~ 10 μm的大毛细孔和> 10 μm的大孔隙所占的比例增加。

    Abstract:

    Carbonation is an important factor affecting the durability of cement-solidified heavy metal-contaminated soils. In order to explore the influence of carbonation on the strength of solidified contaminated soils, lead-contaminated soils were artificially prepared, and carbonation tests were carried out after cement solidification treatment. The effects of carbonation and compactness on unconfined compressive strength of solidified soils were analyzed, and the effects of carbonation on micro mineral morphology and micro pore structure were also analyzed by electron microscope scanning and mercury injection tests. The test results show that unconfined compressive strength of solidified lead-contaminated soils decreases under carbonation, the strength of solidified soils with 15% cement content is reduced by 44% ~ 45%, which is the result of the filling enhancement effect of carbonation reaction products and the weakening of cementation between soil particles. There is a good power function relationship between unconfined compressive strength and porosity of solidified soils, which reveals the influence of filling on strength of solidified soils. Under carbonation, crystalline carbonation reaction product CaCO3 is observed, the total pore volume of solidified soils decreases, the proportion of gel pores less than 0.01μm and capillary pores between 0.01μm and 0.1μm decreases, and the proportion of capillary pores between 0.1μm and 10μm and macro pores greater than 10μm increases.

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  • 收稿日期:2022-04-18
  • 最后修改日期:2022-07-14
  • 录用日期:2022-08-09
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