MICP修复重金属污染溶液及矿化垃圾土试验研究
CSTR:
作者:
作者单位:

1.华中科技大学 岩土与地下工程研究所;2.武汉大学 土木建筑工程学院

中图分类号:

TU375.4

基金项目:

国家重点研发计划课题(NO.2018YFC1802302)


Experimental investigation on bioremediation of heavy metal contaminated solutions and aged refuse by MICP
Author:
Affiliation:

1.Institute of Geotechnical and Underground Engineering,Huazhong University of Science and Technology;2.School of Civil Engineering,Wuhan University,Wuhan

Fund Project:

National Key Research and Development Program (No. 2018YFC1802302)

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    摘要:

    我国不少垃圾填埋场经过“超长服役”,产生了许多新的环境问题。重金属含量较高的垃圾渗滤液易对填埋场周边水体造成污染,填埋场开采扩容产生的矿化垃圾土也具有Cd、Pb、Zn和Cr(Ⅲ)等重金属超标现象,在资源化利用过程中容易造成二次污染,因此垃圾填埋场重金属污染问题亟待解决。近年来,MICP技术固定重金属的能力被广泛探究,其中巴氏芽孢杆菌因环境适应性强,脲酶表达量高而备受关注。但相关研究中的修复对象主要为污染溶液和普通污染土壤,其与垃圾渗滤液以及矿化垃圾土在污染成因和化学成分等方面明显不同。鉴于此,本研究开展巴氏芽孢杆菌修复重金属污染溶液和污染矿化垃圾土试验,探究巴氏芽孢杆菌生物修复重金属的可行性,分析生物修复前后矿化垃圾土中重金属形态变化以及修复机理。结果显示,巴氏芽孢杆菌对溶液中Cd、Pb、Zn和Cr(Ⅲ)去除率可分别达到95%、84%、5%和98%,对矿化垃圾土中可交换态Cd、Pb、和Zn去除率亦可分别达到74%、84%、62%,可交换态Cr(Ⅲ)修复处理前含量几乎为0;经生物修复,矿化垃圾土中可交换态和碳酸盐结合态重金属含量降低,铁锰氧化物结合态和残渣态重金属含量增加;同时,矿化垃圾土中含Fe成分和MICP过程产生的碳酸钙沉淀共同促进重金属向更稳定形态转化。

    Abstract:

    Many landfills in China have undergone "extended service", resulting in many new environmental problems. High heavy metal content landfill leachate can easily cause pollution to the surrounding water bodies of landfills. The aged refuse generated by the expansion of landfill mining also exhibits excessive heavy metals such as Cd, Pb, Zn, and Cr (III), which can easily cause secondary pollution during resource utilization. Therefore, the problem of heavy metal pollution in landfill sites urgently needs to be addressed. In recent years, the ability of MICP technology to immobilize heavy metals has been extensively explored and sporosarcina pasteurii has attracted attention due to its strong environmental adaptability and high expression of urease. However, the remediation objects in related studies are mainly contaminated solutions and ordinary soil, which are obviously different from aged refuse in terms of pollution causes and chemical composition. In view of this, this research carried out experiments on bioremediation of heavy metal contaminated solutions and aged refuse, explored the bioremediation feasibility of heavy metals by s. pasteurii, and analyzed the changes in the fraction of heavy metals before and after bioremediation and the remediation mechanism. The results show that removal rates of Cd, Pb, Zn, and Cr (III) in the solutions by s. pasteurii could reach 95%, 84%, 5%, and 98%, respectively.Also the removal rates of exchangeable Cd, Pb,and Zn in aged refuse could reach 74%, 84%, and 62% , respectively , and the content of exchangeable Cr (III) before remediation is almost 0. The content of exchangeable and carbonate-bound heavy metals in the aged refuse is reduced, and the content of the iron-manganese oxide-bound state and residues are increased after bioremediation. Meanwhile, The Fe content in the aged refuse and the calcium carbonate precipitation produced by the MICP process jointly promote the conversion of heavy metals to a more stable fraction.

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  • 收稿日期:2023-06-28
  • 最后修改日期:2023-09-22
  • 录用日期:2023-10-16
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