早期养护条件对水泥石碳硫硅钙石型硫酸盐腐蚀的影响
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重庆市自然科学基金重点资助项目(CSTC2007BA7019)


Effect of Initial Curing Conditions on Thaumasite Form of Sulfate Attack of Cementitious Materials
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    摘要:

    研究了早期高湿度空气养护、水中标准养护及密封养护对水泥石碳硫硅钙石型硫酸盐腐蚀的影响。采用X射线衍射 (XRD)、 傅立叶转换红外光谱 (FTIR)和扫描电子显微镜(SEM)等方法分析了水泥石经180 d硫酸盐侵蚀后的腐蚀产物。结果表明,早期高湿度空气养护,水泥石碳化生成的CaCO3填充于孔隙中,使表层结构更加致密,阻碍了SO42-等有害离子侵入,延缓了水泥石碳硫硅钙石型硫酸盐腐蚀过程。比较而言,早期密封养护,水泥水化不充分,水泥石内部缺陷相对较多,SO42-等有害离子容易侵入,水泥石碳硫硅钙石型硫酸盐腐蚀最为严重。

    Abstract:

    The effects of initial high humid aircuring, standard watercuring and sealedcuring on thaumasite form of sulfate attack (TSA) of cementbased materials were studied.The Erosion products after 180 days attack in sulfate solution were analyzed by the way of Xray diffraction(XRD) and fourier transform infrared spectroscopy(FTIR).And it was found that the TSA of the cement stone was delayed in high humid air resulting from that CaCO3 generated from carbonation was filled in the pores of the specimens, forming a compacted surface and restricting SO42- intrusion.In comparison, the extent of TSA of the specimens cured in sealed condition was most severe resulting from that large amount of interdefects in specimens for the lower hydration degree, and SO42- ions could intrude into specimens more easily.

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杨长辉,张靖,叶建雄,吴芳,陈科.早期养护条件对水泥石碳硫硅钙石型硫酸盐腐蚀的影响[J].土木与环境工程学报(中英文),2010,32(2):135-139. YANG Changhui, ZHANG Jing, YE Jianxiong, WU Fang, CHEN Ke. Effect of Initial Curing Conditions on Thaumasite Form of Sulfate Attack of Cementitious Materials[J]. JOURNAL OF CIVIL AND ENVIRONMENTAL ENGINEERING,2010,32(2):135-139.10.11835/j. issn.1674-4764.2010.02.025

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  • 收稿日期:2009-12-28
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