A 33-hour field test of outdoor thermal environment was carried out in a typical teaching building cluster located in the hot and humid zone in summer. From the experiment results of local climate data, air temperature, humidity, wind velocity and wet bulb globe temperature (WBGT) at the pedestrian-level, and the typical ground surface temperature, the main characteristics of summer outdoor thermal environment of teaching building cluster in hot and humid zone are obtained. The results show that the patio, overhead and porous pavement can reduce the pedestrian air temperature and WBGT effectively at summer daytime. And the function of the following design methods to improve the outdoor thermal comfort at the summer daytime has the order like overhead>patio>porous pavement>imporous pavement>concrete road. The WBGT at all measuring points at nighttime are almost the same. The test results are further used to verify the existing mathematical models of outdoor velocity and WBGT. The results show that the relative errors are within 6%. Then, the calculation values are in good agreement with the experimental values.