Immersion in sodium chloride solution was adopted to periodically test chloride ion concentration at the surface of concrete and regression analysis was completed.And timedependent law of surface chloride ion concentration of concrete with time was investigated.Influences of sodium chloride solution concentration, water to cement ratio and fly ash content on size and accumulation rate of surface chloride ion concentration were also analyzed.It is found that surface chloride ion concentration gradually grows with the of time increase the of time and reaches a steady state finally.With the increase of sodium chloride solution concentration, surface chloride ion concentration reaches the steady state more quickly and then increases numerically.Bigger water to cement ratio means quicker accumulation of surface chloride ion concentration and greater surface chloride ion concentration.Fly ash replacement could fasten accumulation of surface chloride ion concentration and surface chloride ion concentration increases with the increase of fly ash content.An improved model was proposed by comparison and correction of current models.