Adiabatic temperature rise of mass concrete is effected by many factors. Among those factors, the analysis of cement fineness and components is lacking. Influences of cement fineness, alkali content, replacement of fly ash, and gypsum content on temperature rise of concrete were investigated. The test results show that, temperature rise and temperature rise rate are improved with the increment of specific surface area of cement. When alkali content is ranging from 0.4% to 1.2%, the maximum temperature is reduced with the increment of alkali content, and the temperature-time will be extended whether too high or too low alkali content in cement. The increment of replacement of fly ash and gypsum content is good for reducing temperature rise of concrete.