Density Functional Theory Compute on Electronegativities to Superconductivity of Oxides
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O511 TM262

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    Abstract:

    In this article we have worked out the correlation between electronegativity and high temperature superconductivity for oxide. It is suggested the equalized electronegativity, X cq , can be used as a empirical criterion for superconductivities of oxides. For determining the X cq , a new formula for the calculation of X cq values has been obtained The X cq values of 230 oxide superconductors have been calculated. The result shows that the X cq values of all the oxide superconductors concentrate in a narrow range from 5.00 to 5.63 and that the oxides with values out side this region would be non-superconductive. This criterion can be applied to almost all the oxide superconductors. It is clearly that this result is able to benefit further inquiries about the mechanism of superconductivity.

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洪全.电负性的密度泛函理论计算值与氧化物超导电性[J].重庆大学学报,2001,24(6):117~119

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  • Received:
  • Revised:June 27,2001
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