According to the industrial character of old industrial basement, such as Chongqing, we select preliminarily the candidated inferior position industries by using DEA analyse model. The synthetical basical coefficient of candidated inferior industries is obtained by analysing their indices such as income elasticity of demand, compared superiority coefficient, compared rate coefficient and technical progress rate, etc. Finally determine inferior industries which was supposed to exit by considing fully society progress and continuable development. A new idea are provided for industral structure adjustment for old industrial basement in China.