Based on L.A.Zadeh's idea of fuzzy probability operation in his language probability which space is fuzzy probability,the concrete algorithm of the second kind fuzzy reliability of engineering structure/system is researched.The calculating equation of the fuzzy probabiliy of the second kind fuzzy reliability is given out by using the extension principle for fuzzy sets.The fuzzy set decompose theorem,which satesfies the closed probability operation,is given out and proved.The method calculating fuzzy reliability of that structure/system is studied,where the resistance and load effect of the structure/system have probability.The analysis indicates that the calculation of the second kind fuzzy reliability for a structure/system can be transformed into a series of solving optimum programming.The result of the example indicates the rationality of above algorithm.