To solve potential scheduling problems in production after renewal of continuous casting process in Vanadium-extracting and Steel-making Plant of Panzhihua Iron and Steel Corporation (PISCO), how to model and simulate logistics system in steel-making processhas been discussed. A series of simulatingtests for logistics system in steel-making processhave been conducted based on inputs of presentsteel-making processof PISCO. In the tests, cases of regular schedule case and cases with repairing converter have also been regarded as essential simulation condition. It has been shown that three casters can not start at same time in order to ensure continuous hot metal supply for casters when three kinds of steel are made. It has also been shown that the simulation system for logistics system in steel-making processis valid and can be used for simulating logisticsin upcoming 100% continuous casting process of PISCO. The better schedule scheme of production and reasonable match of converter-caster in time and capacity can be achieved with the help of using simulation approach.