With trait of late landfill leachate treated hardly, it is an effective method of enhancing biodegradability of late landfill leachate that electrolytic oxidation pretreats late landfill leachate, and it is very necessary to calculate current efficiency. Varity of organic pollutants in the late landfill leachate is studied under the electrochemical action by some tests and current efficiency under different electrolytic condition is calculated. The results show that the most high current efficiency is 34.11% when the current density is 15 mA/cm^2 and electrolytic time is 6.5 h.