In order to improve combustion efficiency of natural gas(NG) and reduce pollution emission in nature gas engine, additional injection of hydrogen peroxide (H2O2) into the premix chamber is proposed. With the test of CO, HC and NOx concentration, exhaust temperature, NG consumption etc., it is found that the emission of HC、CO and NOx decreased and the dynamic and economic performance of CNG engine is improved. H2O2 can make reduction of the combustion temperature while increase of the oxygen concentration. The pivot factors affecting NOx emission are temperature and oxygen concentration. The optimum mass proportion of nature gas and H2O2 is between 4.5 and 5.8 for NG consumption and pollution emission.