The research on volume conductive model can be used in designing the conductive systems and optimizing the energy transfer parameters. By considering the coupling of circuit, electromagnetic-field and temperature-field, a 3-D multi-filed coupling model is developed. On the circuit level, the simulation of volume conduction, real-time monitoring for the temperature of skin tissue are achieved, which provides direct theoretical guidance for energy transfer optimization design. With the software FEM 3.5, a volume conduct multi-field coupling model is built to verify the feasibility of volume conduction, which also lays foundation for further optimize energy transfer efficiency.