An adaptive inverse control method for feed water and superheated steam temperature of supercritical pressure boiler is investigated. Through the analysis of the boiler system ,s dynamic characteristics, the input vector structure of inverse dynamics model of feed water and superheated steam temperature is constructed. The adaptive inverse control system is realized through on-line identification of inverse dynamic model with recursive least squares support vector machine. In the control process, the demand for feed water and spray water flow to the outlet steam temperature and micro-superheated steam temperature is considered to realize the integrated control of feed water and superheated steam temperature. Simulation results show that this control system has good control performance and adaptability and can void the repeated oscillation phenomena of control variables which appear in present two section control system.