This paper calibrates the advanced injector angle and EGR of a four-in-line pressure engine on the specialized test stand, which makes the NOx achieved the standard of Euro IV. Then an experiment study of the diesel oxidation catalyst (DOC) and the particulate oxidation catalyst (POC) are made. Both make the diesel engine emission achieving the Standard of Euro IV. This experiment study shows a kind of method that realizing diesel engine emission standard of Euro IV, and concludes the character and law of the method.