Different loadings of WO₃/SBA-15 and WO₃-ZrO₂/SBA-15 are prepared by sol-gel method and characterized by XRD, BET, TEM. The activity of photodegradation of rhodamine B and the adsorption of ammonia ability are investigated. The results show that the rhodamine B is photodegraded easily by using W_x/SBA-15 (x=20,30,40,50) and W₄₀Zr_y/SBA-15 (y=3,5,7,9). Photocatalytic activity from high to low is W₄₀/SBA-15>W₅₀/SBA-15>W₃₀/SBA-15>W₂₀/SBA-15,while doped into ZrO₂,Photocatalytic activity from high to low become W₄₀Zr₅/SBA-15>W₄₀Zr_9/SBA-15>W₄₀Zr₇/SBA-15>W₄₀Zr₃/SBA-15. The rate of photodegradation with W₄₀/SBA-15 and W₄₀Zr₅/SBA-15 are 73.4% and 86.6% respectively. WO₃/SBA-15and WO₃-ZrO₂/SBA-15 also have good cycle efficiency and the advantage of reusability.