Research progress in preparation and doping modification of α-Fe2O3
CSTR:
Author:
Clc Number:

X703;O644.1

  • Article
  • | |
  • Metrics
  • |
  • Reference [77]
  • |
  • Related [20]
  • |
  • Cited by
  • | |
  • Comments
    Abstract:

    Nano-iron oxide (α-Fe2O3) is characterized by its stable chemical properties, environmental friendliness, low preparation cost, and narrow band gap, which makes it an ideal visible-light catalyst. The article introduces the research progress of different preparation methods of α-Fe2O3, with an emphasis on the preparation process of some special structures. The research focuses on the effects of different dopants on photocatalytic performance for degradation of organic pollutants and on their enhancement mechanism as well. Also, the development trends and application prospection of doped α-Fe2O3 are summarized.

    Reference
    [1] Frank S N, Bard A J. Heterogeneous photocatalytic oxidation of cyanide ion in aqueous solutions at titanium dioxide powder[J]. Cheminform, 1977, 8(14):303-304.
    [2] Sundaramurthy J, Kumar P S, Kalaivani M, et al. Superior photocatalytic behaviour of novel 1D nanobraid and nanoporous α-Fe2O3 structures[J]. RSC Advances, 2012, 2(21):8201-8208.
    [3] Mishra M, Chun D M. α-Fe2O3 as a photocatalytic material:a review[J]. Applied Catalysis A:General, 2015, 498:126-141.
    [4] 邢丽贞, 冯雷, 陈华东.光催化氧化技术在水处理中的研究进展[J]. 水科学与工程技术,2008(1):7-10. XING Lizhen, FENG Lei, CHEN Huadong. Advances in photocatalytic oxidation technology in water treatment[J]. Water Sciences and Engineering Technology, 2008(1):7-10. (in Chinese)
    [5] Zeng J, Li J, Zhong J, et al. Improved sun light photocatalytic activity of alpha-Fe2O3 prepared with the assistance of CTAB[J]. Materials Letters, 2015, 160:526-528.
    [6] Ye C, Hu K, Niu Z, et al. Controllable synthesis of rhombohedral α-Fe2O3 efficient for photocatalytic degradation of bisphenol A[J]. Journal of Water Process Engineering, 2019, 27:205-210.
    [7] Fu Y, Li Y, Hu J, et al. Photocatalytic degradation of acetochlor by α-Fe2O3 nanoparticles with different morphologies in aqueous solution system[J]. Optik-International Journal for Light and Electron Optics, 2018(178):36-44.
    [8] Ghasemi E, Ziyadi H, Afshar A M, et al. Iron oxide nanofibers:a new magnetic catalyst for azo dyes degradation in aqueous solution[J]. Chemical Engineering Journal, 2015, 264:146-151.
    [9] 陈喜娣, 蔡启舟, 尹荔松, 等. 纳米α-Fe2O3光催化剂的研究与应用进展[J]. 材料导报, 2010(21):122-128. CHEN Xidi, CAI Qizhou, YIN Lisong, et al. Progress in research and application of nano-hematite photocatalyst[J]. Materials Review, 2010(21):122-128. (in Chinese)
    [10] Machala L, Tucek J, Zboril R. ChemInform abstract:polymorphous transformations of nanometric Iron(Ⅲ) Oxide:a review[J/OL]. Cheminform, 2011, 42(39)[2019-09-25]. https://doi.org/10.1002/chin.201139208
    [11] Imran M, Abutaleb A, Ali M A, et al. UV light enabled photocatalytic activity of α-Fe2O3 nanoparticles synthesized via phase transformation[J]. Materials Letters, 2020, 258:126748.
    [12] Lassoued A, Dkhil B, Gadri A, et al. Control of the shape and size of iron oxide (α-Fe2O3) nanoparticles synthesized through the chemical precipitation method[J]. Results in Physics, 2017, 7(30):07-15.
    [13] Fouad D E, Zhang C, El-Didamony H, et al. Improved size, morphology and crystallinity of hematite (α-Fe2O3) nanoparticles synthesized via the precipitation route using ferric sulfate precursor[J]. Results in Physics, 2019, 12:1253-1261.
    [14] Schwertmann U, Friedl J, Stanjek H. From Fe (Ⅲ) Ions to ferrihydrite and then to hematite[J]. J Colloid Interface Sci, 1999, 209(1):215-223.
    [15] Supattarasakda K, Petcharoen K, Permpool T, et al. Control of hematite nanoparticle size and shape by the chemical precipitation method[J]. Powder Technology,2013,249:353-359.
    [16] Liang H, Liu K, Ni Y. Synthesis of mesoporous α-Fe2O3 via sol-gel methods using cellulose nano-crystals (CNC) as template and its photo-catalytic properties[J]. Materials Letters, 2015, 159:218-220.
    [17] Shao P, Ren Z, Tian J, et al. Silica hydrogel-mediated dissolution-recrystallization strategy for synthesis of ultrathin α-Fe2O3, nanosheets with highly exposed (1,1,0) facets:a superior photocatalyst for degradation of bisphenol S[J]. Chemical Engineering Journal, 2017, 323:64-73.
    [18] Zhou X, Lan J, Liu G, et al. Facet-mediated photodegradation of organic dye over hematite architectures by visible light[J]. Angew Chem Int Ed Engl, 2012, 51(1):178-182.
    [19] Wang F, Qin X F, Meng Y F, et al. Hydrothermal synthesis and characterization of α-Fe2O3 nanoparticles[J]. Materials Science in Semiconductor Processing, 2013, 16(3):802-806.
    [20] Wu Z, Yang S, Wu W. Shape control of inorganic nanoparticles from solution[J]. Nanoscale, 2016, 8(3):1237-1259.
    [21] Kusior A, Michalec K, Jelen P, et al. Shaped Fe2O3 nanoparticles-synthesis and enhanced photocatalytic degradation towards RhB[J]. Applied Surface Science, 2018, 476:342-352.
    [22] Liu R, Jiang Y, Chen Q, et al. Nickel ions inducing growth of high-index faceted α-Fe2O3 and their facet-controlled magnetic properties[J]. RSC Advances, 2013, 3(22):8261-8268.
    [23] Liu R, Jiang Z, Liu Q, et al. Surface-dependent magnetic behavior of α-Fe2O3 quasi-cubes induced by Mg2+ ions[J]. CrystEngComm, 2015, 17(37):7107-7112.
    [24] Liu H T, Guo Y K, Wang N N, et al. Controllable synthesis and photocatalytic activity of ultrathin hematite nanosheets[J]. Journal of Alloys and Compounds, 2019, 771:343-349.
    [25] Liu H T, Tong M L, Zhu K L, et al. Preparation and photo-Fenton degradation activity of nickel ions inducing growth of high-index faceted α-Fe2O3 and their facet-controlled magnetic propertie nanorings obtained by adding H2PO4-, SO42-, and citric acid[J]. Chemical Engineering Journal, 2020, 382:123010.
    [26] Liu J, Yang H, Xue X. Preparation of different shaped α-Fe2O3 nanoparticles with large particle of iron oxide red[J]. CrystEngComm, 2018, 21(7):1097-1101.
    [27] Apte S K, Naik S D, Sonawane R S, et al. Synthesis of nanosize-necked structure and α-Fe2O3 and its photocatalytic activity[J]. Journal of the American Ceramic Society, 2007, 90(2):412-414.
    [28] 李秀艳, 徐记各, 李从举. 纳米纤维材料在光催化领域中的研究进展[J]. 材料导报, 2011(23):29-34. LI Xiuyan, XU Jige, LI Congju. Research progress of nanofiber materials in the field of photocatalysis[J]. Materials Reports, 2011, 25(23):25-30. (in Chinese)
    [29] Trpkov D, Panjan M, Kopanja L, et al. Hydrothermal synthesis, morphology, magnetic properties and self-assembly of hierarchical α-Fe2O3 (hematite) mushroom-, cube- and sphere-like superstructures[J]. Applied Surface Science, 2018, 457:427-438.
    [30] Biju C S, Raja D H, Padiyan D P. Glycine assisted hydrothermal synthesis of α-Fe2O3 nanoparticles and its size dependent properties[J]. Chemical Physics Letters, 2014, 610-611:103-107.
    [31] Geng B, Tao B, Li X, et al. Ni2+/surfactant-assisted route to porous α-Fe2O3 nanoarchitectures[J]. Nanoscale, 2012, 4(5):1671-1676.
    [32] 孟庆华,朱亦仁,顾绍玲,等.纳米α-Fe2O3合成及光催化法处理染料中间体废水[J].无机盐工业,2011,43(1):48-51. MENG Qinghua, ZHU Yiren, GU Shaolin, et al. Synthesis of nano-sized α-Fe2O3 and treatment of dye intermediate wastewater by photocatalystic method[J]. Inorganic Chemicals Industry, 2011, 43(1):48-51. (in Chinese)
    [33] Liu Y, Yu H, Zhan S, et al. Fast degradation of methylene blue with electrospun hierarchical α-Fe2O3 nanostructured fibers[J]. Journal of Sol-Gel Science and Technology, 2011, 58(3):716-723.
    [34] Mathevula L E, Noto L L, Mothudi B M, et al. Structural and optical properties of sol-gel derived α-Fe2O3 nanoparticles[J]. Journal of Luminescence, 2017, 192:879-887.
    [35] Mohammadikish M. Hydrothermal synthesis, characterization and optical properties of ellipsoid shape α-Fe2O3, nanocrystals[J]. Ceramics International, 2014, 40(1):1351-1358.
    [36] Li X, Yu X, He J, et al. Controllable fabrication, growth mechanisms, and photocatalytic properties of hematite hollow spindles[J]. The Journal of Physical Chemistry C, 2009, 113(7):2837-2845.
    [37] Xu L, Xia J, Wang K, et al. Ionic liquid assisted synthesis and photocatalytic properties of α-Fe2O3 hollow microspheres[J]. Dalton Transactions, 2013, 42(18):6468-6477.
    [38] 曾淑文, 王文中. α-Fe2O3光电催化分解水研究进展[J].表面技术,2017,46(4):64-70. ZENG Shuwen, WANG Wenzhong. α-Fe2O3 photoelectrocatalytic water decomposition[J]. Surface Technology, 2017, 46(4):64-70. (in Chinese)
    [39] Sivula K, Leformal F, Gr Tzel M. Solar water splitting:progress using hematite (α-Fe2O3) photoelectrodes[J]. Chemsuschem, 2011, 4(4):432-449.
    [40] Houda, Mansour, Radhouane, et al. Co-precipitation synthesis and characterization of tin-doped α-Fe2O3 nanoparticles with enhanced photocatalytic activities[J]. The Journal of Physics and Chemistry of Solids, 2018, 114:1-7.
    [41] Wang D, Jin L, Li Y, et al. Partial oxidation of vacuum residue over Al and Zr-doped α-Fe2O3 catalysts[J]. Fuel, 2017, 210:803-810.
    [42] Suresh R, Giribabu K, Manigandan R, et al. Synthesis of Co2+-doped Fe2O3, photocatalyst for degradation of pararosaniline dye[J]. Solid State Sciences, 2017, 68:39-46.
    [43] Satheesh R, Vignesh K, Suganthi A, et al. Visible light responsive photocatalytic applications of transition metal (M=Cu, Ni and Co) doped α-Fe2O3 nanoparticles[J]. Journal of Environmental Chemical Engineering, 2014,2(4):1956-1968.
    [44] 张兆志, 魏雨, 刘辉, 等. Zn、Ni掺杂对制备纳米α-Fe2O3的影响研究[J]. 人工晶体学报, 2010, 39(6):1429-1433. ZHANG Zhaozhi, WEI Yu, LIU Hui, et al. Influence of Zn, Ni doping on preparation of nano α-Fe2O3[J]. Journal of Synthetic Crystals, 2010, 39(6):1429-1433. (in Chinese)
    [45] Xiao Z, Li J, Zhong J, et al. Enhanced photocatalytic decolorization of methyl orange by gallium-doped α-Fe2O3[J]. Materials Science in Semiconductor Processing, 2014, 24:104-109.
    [46] Li H, Niu D, Liu D, et al. Understanding the enhanced photoelectrochemical activity of Ta doped hematite[J]. Journal of Molecular Structure, 2017, 1139:104-110.
    [47] Krehula S, ŠTefaniĆ G, Zadro K, et al. Synthesis and properties of iridium-doped hematite (α-Fe2O3)[J]. Journal of Alloys & Compounds, 2012, 545:200-209.
    [48] Mathevula L E, Mothudi B M, Dhlamini M S. Effect of Er3+ on structural and optical properties of microwave synthesized α-Fe2O3 nanoparticles[J]. Physica B:Condensed Matter, 2020,578, 411698.
    [49] Bagwasi, S, Tian B, et al. Synthesis, characterization and application of bismuth and boron Co-doped TiO2:a visible light active photocatalyst[J]. Chemical Engineering Journal,2013, 217:108-118.
    [50] Bak A, Choi S K, Park A H. Photoelectrochemical performances of hematite (α-Fe2O3) films doped with various metals[J]. Bulletin of the Korean Chemical Society, 2015, 36(5):1487-1494.
    [51] Xiao Z, Li J, Zhong J, et al. Enhanced photocatalytic activity of Bi-doped α-Fe2O3[J]. Journal of Advanced Oxidation Technologies, 2014, 17(1):93-98.
    [52] Zhong J B, Li J Z, Zeng J, et al. Enhanced photocatalytic performance of Ga3+-doped ZnO[J]. Materials Research Bulletin, 2012, 47(11):3893-3896.
    [53] 陈思顺, 陈新华, 丁明洁, 等. α-Fe2O3纳米粉体的掺杂研究[J]. 上海化工, 2005, 30(11):23-24, 28. CHEN Sishun, CHEN Xinhua, DING Mingjie, et al. Study on the adulteration synthesis of nanosized α-Fe2O3[J]. Shanghai Chemical Industry, 2005,30(11):23-24, 28. (in Chinese)
    [54] 王元生.掺杂对纳米氧化铁晶化相的影响[J].功能材料, 1999(1):60-62. WANG Yuansheng. Influence of doping on the structure of iron-oxide nanocrystalline phase[J]. Journal of Functional Materials, 1999(1):60-62. (in Chinese)
    [55] Remya R, Abdul K M. Structural, optical and electrical properties of Cu doped α-Fe2O3 nanoparticles[J]. Materials Chemistry and Physics, 2018, 219:42-54.
    [56] 余燕敏. 基于畜牧废水中抗生素降解的新型功能材料制备与应用研究[D]. 北京:中央民族大学,2017. YU Yanming. Preparation and application of new functional materials based on antibiotic degradation in livestock wastewater[D]. Beijing:Minzu University of China, 2017. (in Chinese)
    [57] Sheng G, Haojie W, Wei Y, et al. Scalable synthesis of Ca-doped α-Fe2O3 with abundant oxygen vacancies for enhanced degradation of organic pollutants through peroxymonosulfate activation[J]. Applied Catalysis B:Environmental, 2020,262:118250.
    [58] Li J, Zhang W, Ran M, et al. Synergistic integration of Bi metal and phosphate defects on hexagonal and monoclinic BiPO4:enhanced photocatalysis and reaction mechanism[J]. Applied Catalysis B:Environmental, 2018. 243:313-321.
    [59] Song Z, Wang B, Yu J, et al. Density functional study on the heterogeneous oxidation of NO over α-Fe2O3, catalyst by H2O2:effect of oxygen vacancy[J]. Applied Surface Science, 2017, 413:292-301.
    [60] Marschall R, Wang L. Non-metal doping of transition metal oxides for visible-light photocatalysis[J]. Catalysis Today, 2014, 225:111-135.
    [61] Demirci S, Yurddaskal M, Dikici T, et al. Fabrication and characterization of novel iodine doped hollow and mesoporous hematite (Fe2O3) particles derived from sol-gel method and their photocatalytic performances[J]. Journal of Hazardous Materials, 2018, 345:27-37.
    [62] Bemana H, Rashid-Nadimi S. Effect of sulfur doping on photoelectrochemical performance of hematite[J]. Electrochimica Acta, 2017, 229:396-403.
    [63] Rioult M, Stanescu D, Fonda E, et al. Oxygen vacancies engineering of Iron oxides films for solar water splitting[J]. The Journal of Physical Chemistry C, 2016,120(14):7482-7490.
    [64] Xia C, Jia Y, Tao M, et al. Tuning the band gap of hematite α-Fe2O3 by sulfur doping[J]. Physics Letters A, 2013, 377(31/32/33):1943-1947.
    [65] Guo L, Chen F, Fan X, et al. S-doped α-Fe2O3 as a highly active heterogeneous Fenton-like catalyst towards the degradation of acid orange 7 and phenol[J]. Applied Catalysis B Environmental, 2010, 96(1/2):162-168.
    [66] Rahman M, Wadnerkar N, English N J, et al. The influence of Ti- and Si-doping on the structure, morphology and photo-response properties of α-Fe2O3 for efficient water-splitting:insights from experiment and first-principles calculations[J]. Chemical Physics Letters, 2014, 592:242-246.
    [67] Pengwei Yan, Jimin Shen, Lei Yuan, et al. Catalytic ozonation by Si-doped α-Fe2O3 for the removal of nitrobenzene in aqueous solution[J]. Separation and Purification Technology,2019,228:115766.
    [68] Huang M C, Chang W S, Lin J C, et al. Magnetron sputtering process of carbon-doped α-Fe2O3 thin films for photoelectrochemical water splitting[J]. Journal of Alloys and Compounds, 2015, 636:176-182.
    [69] Lin H, Liu Y, Deng J, et al. Au-Pd/mesoporous Fe2O3:highly active photocatalysts for the visible-light-driven degradation of acetone[J]. Journal of Environmental Sciences, 2018, 70:74-86.
    [70] Li D, Yan X, Yang M, et al. 4-Mercaptobenzoic acid assisted synthesis of Au-decorated α-Fe2O3 nanopaticles with highly enhanced photocatalytic performance[J]. Journal of Alloys and Compounds, 2018,775:150-157.
    [71] Zhang S, Ren F, Wu W, et al. Size effects of Ag nanoparticles on plasmon-induced enhancement of photocatalysis of Ag-α-Fe2O3 nanocomposites[J]. Journal of Colloid and Interface Science, 2014, 427:29-34.
    [72] Cao S W, Fang J, Shahjamali M M, et al. In situ growth of Au nanoparticles on Fe2O3 nanocrystals for catalytic applications[J]. CrystEngComm, 2012, 14(21):7229-7235.
    [73] Liang H, Jiang X, Chen W, et al. α-Fe2O3/Pt hybrid nanorings and their enhanced photocatalytic activities[J]. Ceramics International, 2014, 40(4):5653-5658.
    [74] Pradhan G K, Sahu N, Parida K M. Fabrication of S, N co-doped α-Fe2O3 nanostructures:effect of doping, OH radical formation, surface area,
    [110] plane and particle size on the photocatalytic activity[J]. Rsc Advances, 2013, 3(21):7912-7920.
    [75] Wang T T, Li Y, Jin L J, et al. Upgrading of coal tar with steam catalytic cracking over Al/Ce and Al/Zr co-doped Fe2O3 catalysts[J]. Journal of Fuel Chemistry and Technology, 2019, 47(3):287-296.
    [76] Rajamohan S, Kumaravel V, Abdel W A, et al. Exploration of Ag decoration and Bi doping on the photocatalytic activity α-Fe2O3 under simulated solar light irradiation[J]. Canadian Journal of Chemical Engineering, 2018, 96:1713-1722.
    Cited by
    Comments
    Comments
    分享到微博
    Submit
Get Citation

赵志伟,谭雅焕,耿聰.纳米α-Fe2O3可见光催化剂的制备及掺杂改性研究进展[J].重庆大学学报,2020,43(12):108~117

Copy
Share
Article Metrics
  • Abstract:
  • PDF:
  • HTML:
  • Cited by:
History
  • Received:December 03,2019
  • Online: December 15,2020
  • Published: December 31,2020
Article QR Code