In the development of low-carbon economy, and the context of carbon labeling system,China’s food enterprises’ willing to pay extra cost on carbon-labelled food becomes one important criterion to measure the level of industrial modernization. Through the investigation and analysis of food industry enterprises, we made the conclusion of energy consumption, technical capacity and government involvement, ISO14000 environmental management certification significantly affecting the enterprises’ willing to pay extra cost of carbon labeling food. We suggest that, at present, the carbon labeling food manufacturing should be more emphasis on external push for the government. And the regular monitoring the enterprise environment management status of government will significantly promote them to invest the technology innovation, and further improve energy efficiency.