The differentiation integration of product and service in supply chain must evolve into innovation-modes of product and service supply chain.In view of the differentiation of integration characteristic of product and service,this paper establishes classification figure of product and service supply chain modes based on the differentiation integration of product and service.Considering the differentiation integration of product and service having significant impact on product and service supply chain,this paper puts forward four kinds of typical modes,which are interactive type of PSSC,derivative type of PSSC,assistant type of PSSC and loose type of PSSC.The paper analyzes the connotation and characteristic of each supply chain modes with actual cases,develops the analysis of the applicable for each supply chain modes,establishes the cooperation relationships conformed to internal relations between supply chain enterprises,and proposes the development countermeasures when enterprises implement the product and service supply chain.