Abstract:In this article we have worked out the correlation between electronegativity and high temperature superconductivity for oxide. It is suggested the equalized electronegativity, X cq , can be used as a empirical criterion for superconductivities of oxides. For determining the X cq , a new formula for the calculation of X cq values has been obtained The X cq values of 230 oxide superconductors have been calculated. The result shows that the X cq values of all the oxide superconductors concentrate in a narrow range from 5.00 to 5.63 and that the oxides with values out side this region would be non-superconductive. This criterion can be applied to almost all the oxide superconductors. It is clearly that this result is able to benefit further inquiries about the mechanism of superconductivity.