According to the demand on just in time(JIT)distribution of chain assembly manufacturing enterprise, cost optimization of backup storage and distribution betimes were analyzed. A backup storage optimization model was formulated and quantitative analysis of the JIT backup storage optimization technology for the process of logistics distribution was carried out. The optimized distribution technique to realize JIT distribution was studied, and the distribution model of logistics center and the distribution algorithm flow were established. Finally, the proposed models were applied in the planning and construction of a logistics center of an electric appliance set chain enterprise with satisfactory results.