pH值调节剂对CO 2吸收富液解吸能耗的影响
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重庆市重点基金资助项目(CSTC,2009BA6067)


Effect of pH controlling method on energy consumption of CO2 desorption from rschsolvent
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    摘要:

    在0.2 mol/L MEA、DEA和MDEA吸收CO2饱和溶液的解吸过程中加入一定量的己二酸和辛二酸,对解吸能耗和CO2析出速率的影响进行了实验.发现加酸后在其它解吸实验条件不变情况下,CO2析出速率加快,且加酸剂量在0~0.6 g范围内,CO2解吸速率与加酸量成正比.对加酸前后的CO2解吸能耗进行了计算和比较,发现在解吸过程加酸后解吸CO2的能耗率明显减少,且能耗减少量随加酸量的增加而增大.研究结果表明,采用pH值调节法可降低CO2解吸过程的能耗,加快解吸速率.

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    Solvent absorption is one of the main commercial methods for CO2 capture. However, the process of solvent regeneration is energy intensive and constitutes the main cost in the whole process. The paper investigates the feasibility of a new method ,which is ,to control the pH value of solvent in reducing the energy consumption in solvent regeneration. Some Selected weak organic acids are added into typical solvents which are MEA, DEA and MDEA. It is found that the energy requirement for the release of CO2 is significantly reduced, which however is sensitive to the type of acid added. Meanwhile, CO2 releases faster as more amount of acids added. PH controlling method is thus potentially applicable in solvent technology.

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杜敏,张力,冯波. pH值调节剂对CO 2吸收富液解吸能耗的影响[J].重庆大学学报,2010,33(8):123-129.

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  • 收稿日期:2010-03-28
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