Mg-3Al-1Zn-(0~0.5)Sr镁合金铸态组织中的第二相研究
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科技部国际合作项目(2008DFR50040);国家自然科学基金资助项目(50725413);重庆科学技术委员会资助项目(CSTC,2011ggB50013,2011jjA50019和2011AC4119);重庆市教委资助项目(KJ120834);重庆大学研究生创新基金资助项目(CDJZR11130024)


An investigation on second phases in the as-cast Mg-3Al-1Zn-(0-0.5)Sr magnesium alloys
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    摘要:

    为系统研究微量Sr对铸态AZ31镁合金组织中第二相的影响,且为含Sr的Mg-Al-Zn系合金设计提供理论基础,通过X射线衍射分析(XRD)、差热分析(DSC)、扫描电镜观察(SEM)和能谱分析(EDS)等手段,对Sr含量为0~0.5(质量分数,%,下同)AZ31镁合金铸态组织中的第二相的类型及形成原因进行了分析。结果表明:铸态AZ31合金中除了Mg17Al12相以外,还存在少量的小块状Mg21(Zn,Al)17相。添加Sr含量为0.1的AZ31合金中存在Mg17Al12、Mg21(Zn,Al)17相以及少量Al4Sr相,添加Sr含量为0.3的合金组织中能观察到Al4Sr、Mg21(Zn,Al)17相以及少量Mg17Al12相,而在添加Sr含量为0.5的合金中仅能观察到Al4Sr和Mg21(Zn,Al)17相,Mg17Al12相的形成受到抑制。此外,层片状共晶Al4Sr相的数量在质量分数为0.3~0.5的区间随着Sr含量的增加显著增多。

    Abstract:

    In order to systematically investigate the effect of Sr addition on the second phases in the as-cast AZ31 magnesium alloy and provide the theoretical basis for the design of the Mg-Al-Zn series alloys containing Sr element,the type and formation theory of second phases in the AZ31 as-cast magnesium alloys with low Sr contents(mass friction of 0.1,0.3,and 0.5) are investigated and analyzed by using scanning electron microscope(SEM),energy dispersive spectrometer(EDS),differential scanning calorimetry(DSC),and X-ray diffractometer(XRD). The results indicate that for the AZ31 as-cast alloy without Sr addition,besides the Mg17Al12 phase,the extra Mg21(Zn,Al)17 phase with small amount is found to exist in the alloy. In addition,the difference both in the volume fraction and the type for the second phases in the AZ31 as-cast alloys with different Sr contents is very obvious. The alloys with the addition of 0.1 and 0.3 Sr(mass friction) mainly consists of the α-Mg,Mg17Al12,Mg21(Zn,Al)17 and Al4Sr phases. However,only the α-Mg,Mg21(Zn,Al)17 and Al4Sr phases are observed for the alloy with the addition of 0.5 Sr(mass friction). Otherwise,the volume fraction of the Al4Sr phase with lamella-like sharps increases with the Sr contents increasing among the 0.3-0.5(mass friction) range.

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吴璐,潘复生,杨明波,宋锴,潘虎成. Mg-3Al-1Zn-(0~0.5)Sr镁合金铸态组织中的第二相研究[J].重庆大学学报,2014,37(3):1-9.

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  • 收稿日期:2013-10-09
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  • 在线发布日期: 2014-04-01
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