转炉中石灰石替代部分石灰对脱磷、炉气成分及氧枪枪位的影响
作者:
中图分类号:

TF718

基金项目:

国家自然科学基金资助项目(51374021);北京科技大学教研项目(JG2014M08)。


The effect of using limestone to displace some lime in converter on dephosphorization efficiency,gas composition and oxygen lance position
Author:
  • 摘要
  • | |
  • 访问统计
  • |
  • 参考文献 [20]
  • |
  • 相似文献 [20]
  • | | |
  • 文章评论
    摘要:

    石灰石替代部分石灰进行转炉炼钢可降低炼钢生产成本、减少CO2排放。为研究其加入量对脱磷、炉气成分和氧枪枪位的影响,进行了石灰石替代比分别为18%、19%、20%、25%、28%、29%、39%、41%的工业试验研究和热力学分析。研究结果表明:①石灰石替换比为25%时脱磷效果较好,终点磷含量为0.016%,比原工艺0.030%的终点磷含量降低了47%;②用石灰石替代部分石灰后煤气开始回收时刻提前1~2 min,煤气回收量增加,且石灰石加入量越大,煤气可回收时刻越早;③采用石灰石替代部分石灰冶炼时,转炉氧枪基本控制枪位由1.7 m升高到1.8 m。

    Abstract:

    Using limestone to displace some lime in converter can decrease the production costs of steelmaking and reduce the emission of carbon dioxide.The industrial tests and thermodynamic analysis were carried out to investigate the effect of limestone substitution ratios (18%,19%,20%,25%,28%,29%,39% and 41%) on the dephosphorization efficiency,converter gas composition and oxygen lance position.The results show that better dephosphorization efficiency can be achieved when the limestone substitution ratio is 25%,and the end point phosphorous content is 0.016%,which is reduced by 47% compared with the original process of 0.030%.Meanwhile,the moment of recovering the converter gas is one to two minutes earlier than before,and the amount of recovered gas increases.Furthermore,the more limestone is added,the earlier recovery time is.The results also show that the oxygen lance control position should be raised from 1.7 m to 1.8 m when using limestone to displace some lime in steelmaking.

    参考文献
    [1] 李宏,曲英.一种在氧气顶吹转炉中用石灰石代替石灰造渣炼钢的方法:中国,ZL 200910082071.X[P].2011-01-19. LI Hong, QU Ying. A technique on limestone instead of lime for slagging in BOF steelmaking process:China, ZL 200910082071. X[P]. 2011-01-19.
    [2] 孟金霞,陈伟庆.活性石灰在炼钢初渣中的熔解研究[J].炼钢,2008,24(2):54-58. MENG Jinxia,CHEN Weiqing. Investigation of active lime liquation in initial slag of steel-making[J]. Steelmaking, 2008, 24(2):54-58. (in Chinese)
    [3] 郭汉杰,尹志明,王宏伟. 冶金活性石灰烧制过程最佳工艺制度[J].北京科技大学学报,2008,30(2):148-151. GUO Hanjie, YIN Zhipeng, WANG Hongwei. Optimum schedule in calcination process of metallurgical active lime[J]. Journal of University of Science and Technology Beijing, 2008, 30(2):148-151. (in Chinese)
    [4] 刘宇,王文科,王鹏,等.转炉采用石灰石部分替代石灰的冶炼实践[J].鞍钢技术,2011(5):41-44. LIU Yu, WANG Wenke, WANG Peng, et al. Steel-making operations by substituting limestone for some limes in converter[J]. Angang Technology, 2011(5):41-44. (in Chinese)
    [5] 李宏,曲英.氧气转炉炼钢用石灰石代替石灰节能减排初探[J].中国冶金,2010,20(9):45-48. LI Hong, QU Ying. Discussion on limestone addition instead of lime for energy-saving and emission reduction in BOF steelmaking[J]. China Metallurgy, 2010, 20(9):45-48. (in Chinese)
    [6] 田志国,汤伟,潘锡泉.转炉采用石灰石替代部分石灰冶炼的应用分析[J].中国冶金,2012,22(7):47-51. TIAN Zhiguo, TANG Wei, PAN Xiquan. Application Analysis of Substituting Limestone for Some Limes in BOF[J]. China Metallurgy, 2012, 22(7):47-51. (in Chinese)
    [7] 石磊,钱高伟,朱志鹏,等.转炉采用石灰石替代部分石灰的工业试验[J].武钢技术,2013,51(4):23-25. SHI Lei, QIAN Gaowei, ZHU Zhipeng, et al. Industrial experiment on substituting limestones for some limes in converter[J]. Wuhan Iron and Steel Corporation Technology, 2013, 51(4):23-25. (in Chinese)
    [8] Deng T, Nortier P, Ek M, et al. Limestone Dissolution in Converter Slag at 1873 K (1600℃)[J]. Metallurgical and Materials Transactions B, 2013, 44(1):98-105.
    [9] Guo L F, Li H, Li Z Q, et al. Discussion on the decomposition laws of limestone during converter steelmaking process by static decomposition model under constant temperature[J]. Advanced Materials Research, 2011, 233/234/235:2648-2653.
    [10] Liu X H, Zhang K F, Li M Z. Research on using lmestone for slagging during BOF steelmaking process[J]. Advanced Materials Research, 2013, 690/691/692/693:237-245.
    [11] Li Y Q, Li H, Guo L F. The influence of decomposition and slagging of limestone to temperature in convertor[J]. Advanced Materials Research, 2012, 490/491/492/493/494/495:3836-3839.
    [12] Feng J, Li H, Li C X, et al. Research on using limestone for slagging during BOF steelmaking process[J]. Advanced Materials Research, 2013, 690/691/692/693:237-245.
    [13] 爱歇尔.底吹碱性转炉炼钢法[M].北京:中国工业出版社,1964. Eichel. Basic bottom blowing converter steelmaking method[M]. Beijing:China Industry Press, 1964. (in Chinese)
    [14] Kharlashin P S, Nosochenko O V, Zguriev L L, et al. Huge phosphor hot metal refining in 360-ton converter using lump limestone[J]. Steel in Translation, 1991(4):19-20.
    [15] 李宏,冯佳,李永卿,等.转炉炼钢前期石灰石分解及CO2氧化作用的热力学分析[J].北京科技大学学报,2011,33(Sup1):83-87. LI Hong, FENG Jia, LI Yongqing, et al. Thermodynamic analysis of limestone decomposition and CO2 oxidation effect in the early stage of BOF steelmaking[J]. Journal of University of Science and Technology Beijing, 2011, 33(Sup1):83-87. (in Chinese)
    [16] 刁江. Al2O3和Na2O对高磷铁水脱磷的影响[J]. 钢铁研究学报,2013,25(2):9-13. DIAO Jiang. Effect of Al2O3 and Na2O on dephosphorization of high phosphorus hot metal[J]. Journal of Iron and Steel Research, 2013, 25(2):9-13. (in Chinese)
    [17] 王新华.钢铁冶金:炼钢学[M].北京:高等教育出版社,2011. WANG Xinhua. Ferrous metallurgy:steelmaking[M]. Beijing:Higher Education Press, 2011. (in Chinese)
    [18] Basu S, Kumar L A, Seetharaman S. A model for activity coefficient of P2O5 in BOF slag and phosphorus distribution between liquid steel and slag[J]. Isij International, 2007, 47(8):1236-1238.
    [19] Niekerk W H V, Dippenaar R J. Phosphorus distribution between carbon-saturated iron at 135℃ and lime-based slags containing Na2O and CaF2[J]. Metallurgical and Materials Transactions B, 1998, 29(1):147-153.
    [20] 徐匡迪,肖丽俊.转炉铁水预处理脱磷的基础理论分析[J].上海大学学报(自然科学版),2011,17(4):331-336. XU Kuangdi, XIAO Lijun. Theoretical analysis of hot metal dephosphorization pretreatment in converter[J]. Journal of Shanghai University (Natural Science), 2011, 17(4):331-336. (in Chinese)
    引证文献
    网友评论
    网友评论
    分享到微博
    发 布
引用本文

梁永昌,唐海燕,刘威,杨宏博,郭森林,汪国奉,党进乾,李京社.转炉中石灰石替代部分石灰对脱磷、炉气成分及氧枪枪位的影响[J].重庆大学学报,2017,40(6):8-14.

复制
分享
文章指标
  • 点击次数:1035
  • 下载次数: 1475
  • HTML阅读次数: 440
  • 引用次数: 0
历史
  • 收稿日期:2015-12-23
  • 在线发布日期: 2017-06-29
文章二维码