+高级检索
首页 > 过刊浏览>2018年第41卷第12期 >92-100. DOI:10.11835/j.issn.1000-582X.2018.12.011
PDF HTML阅读 XML下载 导出引用 引用提醒
锂离子电池负极材料Li4Ti5O12的研究进展
作者:
中图分类号:

TQ174

基金项目:

中央高校基本科研基金（0301005202017）；国家青年千人计划（0220002102003）；国家自然科学基金资助项目（21373280，21403019）；北京分子科学国家实验室和重庆大学百人计划（0903005203205）；机械传动国家重点实验室项目（SKLMT-ZZKT-2017M11）。


Progress in the research on anode material Li4Ti5O12 for Li-ion batteries
Author:
  • 摘要
    • | |
  • 访问统计
    • |
  • 参考文献 [32]
    • |
  • 相似文献 [20]
    • | | |
  • 文章评论
    摘要:

    Li4Ti5O12材料具有稳定、安全、寿命长等显著优点，是锂离子电池负极材料的研究热点。介绍了Li4Ti5O12的结构特点和储能机制，对制备Li4Ti5O12的高温固相合成法、微波合成法、溶胶凝胶法以及其他制备方法进行讨论和概述，同时对离子掺杂、表面包覆和形貌调控等改性研究进行了总结和评述。最后，对Li4Ti5O12的发展前景进行了展望。

    Abstract:

    The material Li4Ti5O12 with its advantages of stability, safety, long life, etc., has been the research focus of anode material for lithium ion batteries. In this paper, the structural features and energy storage mechanism of Li4Ti5O12 were introduced. The solid state method, microwave method, sol-gel method and other preparation methods of Li4Ti5O12 were discussed and summarized. And some modification methods of Li4Ti5O12, such as ion doping, surface coating and morphological control, were summarized and reviewed as well. Finally, the prospects for the development of Li4Ti5O12 were discussed.

    参考文献
    [1] 王朔,周格,禹习谦,等.储能技术领域发表文章和专利概览综述[J].储能科学与技术,2017, 6(4):810-838. WANG Shuo, ZHOU Ge, YU Xiqian, et al. Overview of research papers and patents on energy storage technologies[J]. Energy Storage Science and Technology,2017,6(4):810-838.(in Chinese)
    [2] 滕吉文,张永谦,阮小敏.发展可再生能源和新能源与必须深层次思考的几个科学问题:非化石能源发展的必由之路[J].地球物理学进展, 2010, 25(4):1115-1152. TENG Jiwen, ZHANG Yongqian, RUAN Xiaomin. Some improtant sciemtific problems for development of renewable and new energy:The only way for development of non-fossil energy[J]. Progress in Geophysics, 2010, 25(4):1115-1152.(in Chinese)
    [3] 闫金定.锂离子电池发展现状及其前景分析[J].航空学报, 2014, 35(10):2767-2775. YAN Jinding. Current status and development analysis of lithium-ion batteries[J]. Acta Aeronautica ET Astronautica Sinica, 2014, 35(10):2767-2775. (in Chinese)
    [4] 杨斌, 阮殿波, 傅冠生, 等.钛酸锂(Li4Ti5O12)负极材料的研究进展[J].材料导报, 2015, 29(S1):157-162. YANG Bin, RUAN Dianbo, FU Guansheng, et al. Development of Li4Ti5O12 for Anode Materials[J]. Materials Review, 2015, 29(S1):157-162.(in Chinese)
    [5] 季俊红, 秦国强, 齐满富, 等. Li4Ti5O12负极材料的制备及应用研究进展[J].电池工业, 2017,21(5):45-49. JI Junhong, QIN Guoqiang, QI Manfu, et al. Preparation and application progress of Li4Ti5O12 anode material[J]. Chinese Battery Industry, 2017,22(5):45-49.(in Chinese)
    [6] 成庆堂, 李洪森, 申来法, 等.锂离子电池负极材料Li4Ti5O12研究进展[J].电源技术, 2015, 39(1):188-190. CHENG Qingtang, LI Hongsen, SHEN Laifa, et al. Research progress on anode material Li4Ti5O12 for Li-ion batteries[J]. Chinese Journal of Power Sources, 2015, 39(1):188-190. (in Chinese)
    [7] Ohzuku T. Zero-strain insertion material of Li-[Li1/3Ti5/3]O4 for rechargeable lithium cells[J]. Journal of the Electrochemical Society, 1995, 142(5):1431.
    [8] Sorensen E M, Barry S J, Jung H K, et al.Three-dimensionally ordered macroporous Li4Ti5O12:effect of wall structure on electrochemical properties[J]. Chemistry of Materials,2006(2):482-489.
    [9] Lin C Y, Duh J G. Porous Li4Ti5O12 anode material synthesized by one-step solid state method for electrochemical properties enhancement[J]. Journal of Alloys and Compounds, 2011, 509(8):3682-3685.
    [10] Yao X L, Xie S, Nian H Q, et al. Spinel Li4Ti5O12 as a reversible anode material down to 0V[J]. Journal of Alloys and Compounds, 2008, 465(1/2):375-379.
    [11] Li X, Qu M Z, Huai Y J, et al. Preparation and electrochemical performance of Li4Ti5O12/carbon/carbon nano-tubes for lithium ion battery[J]. Electrochimica Acta, 2010, 55(8):2978-2982.
    [12] Baohua Li, Feng Ning, Yan-Bing He, et al. Synthesis and Characterization of Long Life Li4Ti5O12/C Composite Using Amorphous TiO2 Nanoparticles[J]. International Journal of Electrochemical Science,2011,6:3210-3223.
    [13] Li J, Jin Y L, Zhang X G, et al. Microwave solid-state synthesis of spinel Li4Ti5O12 nanocrystallites as anode material for lithium-ion batteries[J].Solid State Ionics, 2007, 178(29/30):1590-1594.
    [14] Chou S L, Wang J Z, Liu H K, et al. Rapid synthesis of Li4Ti5O12 microspheres as anode materials and its binder effect for lithium-ion battery[J]. The Journal of Physical Chemistry C, 2011, 115(32):16220-16227.
    [15] Liu J, Li X F, Yang J L, et al. Microwave-assisted hydrothermal synthesis of nanostructured spinel Li4Ti5O12 as anode materials for lithium ion batteries[J]. Electrochimica Acta, 2012(63):100-104.
    [16] Qiao Y, Hu X L, Liu Y, et al. Li4Ti5O12 nanocrystallites for high-rate lithium-ion batteries synthesized by a rapid microwave-assisted solid-state process[J]. Electrochimica Acta, 2012(63):118-123.
    [17] Shen C M, Zhang X G, Zhou Y K, et al. Preparation and characterization of nanocrystalline Li4Ti5O12 by sol-gel method[J]. Materials Chemistry and Physics, 2003, 78(2):437-441.
    [18] Hao Y J, Lai Q Y, Xu Z H, et al. Synthesis by TEA sol-gel method and electrochemical properties of Li4Ti5O12 anode material for lithium-ion battery[J]. Solid State Ionics, 2005, 176(13/14):1201-1206.
    [19] Hao Y J, Lai Q Y, Liu D Q, et al. Synthesis by citric acid sol-gel method and electrochemical properties of Li4Ti5O12 anode material for lithium-ion battery[J]. Materials Chemistry and Physics, 2005, 94(2/3):382-387.
    [20] Zhang N Q, Liu Z M, Yang T Y, et al. Facile preparation of nanocrystalline Li4Ti5O12 and its high electrochemical performance as anode material for lithium-ion batteries[J]. Electrochemistry Communications, 2011, 13(6):654-656.
    [21] Peng L, Zhang H J, Fang L, et al. Novel peapoded Li4Ti5O12 nanoparticles for high-rate and ultralong-life rechargeable lithium ion batteries at room and lower temperatures[J]. Nanoscale, 2016, 8(4):2030-2040.
    [22] Tang Y F, Yang L, Fang S H, et al. Li4Ti5O12 hollow microspheres assembled by nanosheets as an anode material for high-rate lithium ion batteries[J]. Electrochimica Acta, 2009, 54(26):6244-6249.
    [23] Tang Y F, Yang L, Qiu Z, et al. Preparation and electrochemical lithium storage of flower-like spinel Li4Ti5O12 consisting of nanosheets[J].Electrochemistry Communications,2008, 10(10):1513-1516.
    [24] He Z J, Wang Z X, Wu F X, et al. Spherical Li4Ti5O12 synthesized by spray drying from a different kind of solution[J]. Journal of Alloys and Compounds, 2012, 540:39-45.
    [25] Zhu G N, Liu H J, Zhuang J H, et al. Carbon-coated nano-sized Li4Ti5O12 nanoporous micro-sphere as anode material for high-rate lithium-ion batteries[J]. Energy & Environmental Science, 2011, 4(10):4016-4022.
    [26] Wen S J, Li G J, Ren R M, et al. Preparation of spherical Li4Ti5O12 anode materials by spray drying[J]. Materials Letters, 2015, 148:130-133.
    [27] 连江平,李倩倩,温巧娥,等.锂离子电池负极材料钛酸锂的研究进展[J].新能源进展, 2016, 4(4):297-304. LIAN Jiangping, LI Qianqian, WEN Qiaoe, et al. Research progress on lithium titanate as anode material in lithium-ion battery[J]. Advances in new and renewable energy, 2016, 4(4):297-304. (in Chinese)
    [28] Li X, Qu M Z, Yu Z L. Structural and electrochemical performances of Li4Ti5-xZrxO12 as anode material for lithium-ion batteries[J]. Journal of Alloys and Compounds, 2009, 487(1/2):L12-L17.
    [29] Li S Y, Chen M, Xue Y, et al. Electrochemical properties of citric acid-assisted combustion synthesis of Li4Ti5O12 adopting Cr by the solid-state reaction process[J]. Ionics,2015, 21(6):1545-1551.
    [30] Lai C, Dou Y Y, Li X, et al. Improvement of the high rate capability of hierarchical structured Li4Ti5O12 induced by the pseudocapacitive effect[J]. Journal of Power Sources,2010, 195(11):3676-3679.
    [31] Hui Y N, Cao L Y, Xu Z W, et al. Synthesis of Li4Ti5O12 nanoclusters for lithium-ion batteries with excellent electrochemical performances[J]. Journal of Electroanalytical Chemistry, 2016, 763:32-36.
    [32] 吕岩,张浩,曹高萍,等.酚醛树脂为碳源制备碳包覆Li4Ti5O12材料[J].电池工业,2010, 15(5):296-299. LYU Yan, ZHANG Hao, CAO Gaoping, et al. Preparation of carbon-coated Li4Ti5O12 composite using phenol formaldehyde resin as the carbon source[J]. Chinese Battery Industry, 2010, 15(5):296-299.(in Chinese)
    引证文献
    网友评论
    网友评论
    分享到微博
    发 布
引用本文

游时利,方玲,许海涛,王煜.锂离子电池负极材料Li4Ti5O12的研究进展[J].重庆大学学报,2018,41(12):92-100.

复制
分享
文章指标
  • 点击次数:834
  • 下载次数: 391
  • HTML阅读次数: 0
  • 引用次数: 0
历史
  • 收稿日期:2018-07-05
  • 在线发布日期: 2018-12-27
文章二维码
您是第11562287 位访问者
主管单位：中华人民共和国教育部
主办单位：重庆大学
地址：重庆市沙坪坝正街174号
电话：
重庆大学学报 ® 2025 版权所有