基于聚乙烯醇水凝胶纤维的自增强各向异性水凝胶的制备和力学性能研究
DOI:
CSTR:
作者:
作者单位:

1.长沙民政职业技术学院;2.重庆大学航空航天学院

作者简介:

通讯作者:

中图分类号:

O 3? ????

基金项目:

国家自然科学(U23A2067)。


Study on the preparation and mechanical properties of self-reinforced anisotropic hydrogels based on poly(vinyl alcohol) hydrogel fibers
Author:
Affiliation:

1.Changsha Social Work College;2.Chongqing university;3.College of Aerospace Engineering,Chongqing University

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    本文针对水凝胶在实际应用中面临的力学性能提升及工业化生产难题展开研究。鉴于传统各向同性水凝胶强韧化方法的局限以及常见纤维增强材料体系的不足,提出一种新的水凝胶纤维制备方法。以商用水溶性聚乙烯醇(polyvinyl alcohol,PVA)纱线为原料,浸渍于含甘油水溶液后经冻融循环制得PVA水凝胶纤维,并测试其拉伸性能。进而将该纤维与PVA水凝胶基体复合,制备出自增强各向异性水凝胶,深入探究了纤维体积分数、基体PVA含量等因素对其力学性能的影响。结果显示,通过优化甘油含量可显著提升PVA水凝胶纤维性能,如甘油质量分数80 wt%时,拉伸强度达54.7 MPa。自增强各向异性水凝胶中,纤维体积分数16%时拉伸强度最大为6.2MPa,且增加基体PVA含量也能改善其力学性能。同时构建了使用此类水凝胶的超弹性本构模型,并结合有限元法验证了其有效性,为水凝胶大规模应用与理论研究提供了新思路。

    Abstract:

    A study on the mechanical property enhancement and industrial production challenges faced by hydrogels in practical applications is carried out in this study. Due to the limitations of traditional isotropic hydrogel toughening methods and the shortcomings of common fiber reinforcing material systems, a new method of hydrogel fiber preparation is proposed. A commercial water-soluble polyvinyl alcohol (PVA) yarn was impregnated with a glycerol-containing aqueous solution and then subjected to a freeze-thaw cycle to produce PVA hydrogel fibers, and its tensile properties were tested. The fibers were then composited with a PVA hydrogel matrix to prepare self-reinforced anisotropic hydrogels, and the effects of the fiber volume fraction, matrix PVA content and other factors on their mechanical properties were investigated in depth. The results showed that the fiber properties of PVA hydrogel could be significantly improved by optimising the glycerol content, such as tensile strength of 54.7 MPa at 80 wt% glycerol mass fraction, and the tensile strength of self-reinforced anisotropic hydrogel was maximum at 6.2 MPa at 16% fiber volume fraction, and the mechanical properties could be improved by increasing the PVA content of the matrix. At the same time, the superelastic intrinsic model using this kind of hydrogel was

    参考文献
    相似文献
    引证文献
引用本文
分享
相关视频

文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2025-01-17
  • 最后修改日期:2025-03-01
  • 录用日期:2025-06-23
  • 在线发布日期:
  • 出版日期:
文章二维码