粘结相含量对TiC基金属陶瓷显微组织和力学性能的影响
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1.重庆大学航空航天学院;2.钒钛关键战略材料四川省重点实验室;3.攀钢集团攀枝花钢钒有限公司轨梁厂;4.四川科力特硬质合金股份有限公司

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国家级大学生创新实验项目(202411360013),四川省中央引导地方科技发展专项项目(2024ZYD0330),攀枝花市省级定向财力转移支付项目(22ZYZF-G-02,21ZYZF-G-01)。


Effect of binder contents on microstructure and mechanical properties of TiC-based cermets
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1.Panzhihua University;2.Sichuan Vanadium Titanium Industrial Technology Institute;3.Pangang Group Panzhihua Steel Vanadium Co,Ltd Rail Beam Factory;4.Sichuan Kelite Cemented Carbide Co,Ltd

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    摘要:

    TiC基金属陶瓷具有密度低、硬度高、抗氧化性能好等优异特性,在硬质刀具和模具中应用广泛。结合X-射线衍射、扫描电镜观察、显微硬度和横向断裂强度测试等方法研究了粘结相含量对TiC基金属陶瓷显微组织和力学性能的影响。结果表明:当粘结相含量为15 wt%时,TiC基金属陶瓷的力学性能最佳,硬度为1668 HV,抗弯强度为1377 MPa,断裂韧性为7.76 MPa/mm1/2。粘结相含量的增加有利于促进液相烧结,但是当粘结相含量增加到21wt%时,液相烧结过程中溶解到粘结相中的碳化物含量增加,导致芯-环结构环相发生粗化,引起材料的综合力学性能下降。

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    Abstract: TiC-based cermets have been widely used in wear parts and cutting tools due to their excellent properties such as low density, high hardness, good high-temperature oxidation resistance and so on. Effect of binder content on the microstructure and mechanical properties of TiC-based cermets was investigated using X-ray diffraction, scanning electron microscopy observation, microhardness tests and transverse rupture strength tests. Results showed that when the binder content was 15wt%, the TiC-based cermet has best mechanical properties. The hardness, flexural strength and fracture toughness are 1668 HV, 1377MPa, 7.76MPa/mm1/2, respectively. Increasing binder content is beneficial to promote liquid sintering. However, when the binder content increased to 21wt%, the content of dissolved carbides in liquid increased, the mechanical properties decreased due to coarsened surrounding rims.

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  • 收稿日期:2025-07-15
  • 最后修改日期:2025-08-06
  • 录用日期:2025-10-09
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