渗碳的传质的数学模型及意义
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TG151

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THE MATHEMATICAL MODEL OF CARBURIZED MASS-TRANSFER AND ITS MEANINGS
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    摘要:

    本文研究了气体渗碳过程中,碳原子由气相到固相传递的动力学。根据固相表面的化学反应动力学方程,推导出碳由气相到固相的传递量正比于气—固相间碳的活度差。由此建立气—固相碳传递的动力学方程,并讨论了碳传递速度的影响团素。可推知,增加气相中一氧化碳和氢气含量可提高碳传递速度,另外,适量氧化介质特别是水可加速碳的传递。

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    This paper deals with the kinetics of carbon atoms transfer from gas phase to solid phase in gas carburizing. According to the kinetic equations of the chemical reactions on the solid surface, it is deduced that the carbon transfer quantity from gas phase to solid phase is in direct proportion to the difference of carbon activiries between gas phase and solid phase. Based on what is mentioned above, we set up the kinetic equation of carbon transfer from gas phase to solid phase, discussed the factors which affected the carbon transfer. It was known then that increasing the contents of carbon monoxide and hydrogen in gas phase could qu'icken the carbon transfer. On the other hand, proper oxidants, especially proper water, could quicken the carbon transfer.

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张丁非 吴恩林.渗碳的传质的数学模型及意义[J].重庆大学学报,1989,12(5):51-58.

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