Al3Ti和TiC/Al3Ti激光熔覆涂层的高温氧化和浸泡腐蚀性能
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广西科学研究与技术开发应用基础专项项目(桂科基0731005)


High-temperature oxidation and immersion corrosion propertiesof Al3Ti and TiC/Al3Ti laser cladding coatings
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    摘要:

    采用激光熔覆技术在铝合金表面制备了Al3Ti金属间化合物和TiC颗粒增强Al3Ti基复合材料涂层,对比分析了两种涂层的高温氧化和浸泡腐蚀性能。结果表明:在稍低于铝合金熔点(600 ℃)循环氧化70 h后,两种涂层均没有明显的氧化增重,显示出较强的抗氧化性。氧化温度为900 ℃时,涂层的氧化增重呈抛物线规律增长,且复合材料涂层的抗氧化性低于Al3Ti涂层。在NaCl质量分数为3.5%的溶液中浸泡15天后,复合材料涂层的腐蚀程度最轻,涂层中的硬质相Al3Ti和TiC抑制了点蚀的扩展,但两种涂层均提高了铝合金的抗腐蚀性能。

    Abstract:

    Intermetallic compound Al3Ti coating and TiC particle-reinforced Al3Ti matrix composite coating are prepared on the surface of aluminum alloys by laser cladding. The high-temperature oxidation and immersion corrosion behaviors of those two coatings are compared. The results show that the coatings exhibit minimal oxidation mass gains during the cyclic oxidation close to the melting point of the substrate(600℃) for 70 h, providing excellent protection to the aluminum alloys. When oxidized at 900℃, the coatings show significant mass gains in accordance with the parabolic law, and the oxidation resistance of the composite coating is lower than that of the Al3Ti coating. After immersed in 3.5 wt% NaCl solution for 15 days, the composite coating presents the less corrosion attack for hard Al3Ti and TiC particles impede the growth of pitting, and both coatings improve the corrosion resistance of the aluminum alloys.

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符跃春,杨智成,王国华,何欢. Al3Ti和TiC/Al3Ti激光熔覆涂层的高温氧化和浸泡腐蚀性能[J].重庆大学学报,2010,33(7):63-67.

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  • 收稿日期:2010-02-15
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