不可采煤层CO2封存的数值模拟
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国家自然科学基金创新研究群体科学基金资助项目(50921063);重庆市院士基金项目(CSTC 2010BC6006);重庆大学“211工程”三期创新人才培养计划建设项目(S-10220)。


Numerical simulation of carbon dioxide storage in unmineable coalbed
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    摘要:

    将CO2注入不可采煤层进行封存(CO2-ECBM)能在封存CO2的同时回收甲烷,因而是一项具有良好前景的CO2处置技术。CO2或者CO2/N2混合气注入煤层后在煤层中运移涉及到多组分气体在煤中的吸附、多组分气体以及气、水两相在煤层中的扩散渗流等过程。基于上述过程,建立了考虑煤基质吸附气体后的膨胀效应、能够描述多组分气体在煤层中吸附/解吸扩散渗流过程的数学模型,并采用数值解法对模型进行了求解,与已有的模拟结果比较表明建立的模型是可靠的;利用该模型研究了煤层渗透率、不同气体差异性吸附膨胀系数、煤对CO2/CH4的吸附比、以及注入气体组成对于CO2封存以及煤层气生产的影响,研究结果可以为CO2-ECBM项目的场地条件选择以及工艺参数的优化提供依据。

    Abstract:

    The injection of carbon dioxide (CO2) in deep unmineable coalbeds(CO2-ECBM) is a very attractive option for geologic CO2storage. The CO2 is stored and at the same time the recovery of coalbed methane is enhanced. The revenue of methane (CH4) production can offset the expenditures of the storage operation. The processes involving in the CO2-ECBM include multi-components gas adsorption,diffusion,and gas-water two phase flow in coalbed. On the basis of above processes,a model considering adsorption induced coal matrix swelling is developed, which can be used to describe multi-components gas adsorption/desorption-diffusion-flow in coalbed. The finite difference method is used to solve this model,and the comparison of the results with the existed model suggests the model is valid. Then the model is applied to evaluated the influence of permeability of coal seam,different gas adsorption induced swelling,CO2/CH4 adsorption capacity ratio,pore model considering matrix swelling,and gas composition of injection gas on CO2 sequestration and methane production, and these results are very important for site selection and technological parameters optimum of CO2-ECBM project.

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周军平,鲜学福,姜永东,刘占芳.不可采煤层CO2封存的数值模拟[J].重庆大学学报,2011,34(7):83-90.

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  • 收稿日期:2011-01-15
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