微塑料对土壤磷吸附的影响
作者:
作者单位:

重庆大学 环境与生态学院,重庆400045

作者简介:

唐子超(1998—),男,硕士,主要从事水污染控制方向的研究,(E-mail)tang1214301012@163.com。

通讯作者:

蒋艳雪,女,讲师,(E-mail)jiangyanxue@cqu.edu.cn。

中图分类号:

X505

基金项目:

国家自然科学基金资助项目(32001195);国家重点研发计划资助项目(2019YFD1100501)。


Effect of microplastics on soil phosphorus adsorption
Author:
Affiliation:

College of Environment and Ecology, Chongqing University, Chongqing 400045, P. R. China

Fund Project:

Supported by National Natural Science Foundation of China(32001195), and the National Key Research and Development Program of China(2019YFD1100501).

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    摘要:

    微塑料是一类土壤中广泛存在的新兴污染物,其对土壤磷吸附的影响尚不明确。文中分析了0.1%~10%含量微塑料对土壤磷吸附特性的影响及机制。结果表明,微塑料会使得吸附第一阶段液膜扩散阶段速率显著提升(p<0.05)。与纯土壤(qe=6.456 mg/g)相比,含量1%以下的微塑料显著降低了土壤磷吸附容量(p<0.05),但5%以上的微塑料显著提升了土壤磷吸附容量(p<0.05)。同等含量下,微塑料粒径越小,微塑料-土壤体系的磷吸附量越大。微塑料可与磷竞争吸附位点,降低了微塑料-土壤体系对磷的吸附,但微塑料也可直接吸附磷,故当微塑料为5%及以上时,微塑料-土壤体系对磷的吸附量升高。因此,土壤微塑料污染可显著改变土壤对磷的吸附特性,且与微塑料的含量和粒径等因素密切相关。

    Abstract:

    Microplastics are emerging pollutants widely present in soil, and their effects on soil phosphorus (P) adsorption are still unclear. This paper examined the effects of 0.1% to 10% microplastics on soil P adsorption and the underlying mechanisms. The results showed that microplastics could significantly increase the rate of liquid film diffusion stage in the first stage of the adsorption process (p<0.05). Compared with the pure soil (qe=6.456 mg/g), the soil P adsorption capacity was significantly reduced by microplastics with less than 1% concentration (p<0.05). However, the soil P adsorption capacity was significantly increased by microplastic with concentrations higher than 5% (p<0.05). Additionally, the smaller the particle size of microplastics, the greater the P adsorption capacity of soil with the same microplastic concentration. Microplastics could compete with P for adsorption sites, which reduced the adsorption of P in the microplastic-soil system. However, microplastics could also directly adsorb P, leading to an increase in the P adsorption capacity of microplastic-soil system when microplastic concentration were more than 5%. Therefore, microplastics pollution in soil could significantly change P adsorption characteristics, which closely related to the microplastics concentration and particle size.

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唐子超,唐晋,梁伦套,黎彦均,蒋艳雪,方芳,郭劲松.微塑料对土壤磷吸附的影响[J].重庆大学学报,2024,47(4):12-21.

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  • 收稿日期:2023-03-13
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  • 在线发布日期: 2024-05-06
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