This paper was derived from the author’s teaching work. Through studying the silicate structural chemistry containing silica minerals of H+ related chemical structure, it can be found that the H+ ions in mineral can be structured with the O2- ions formatting (OH)- ion or H2O water molecules, which make a possible to change classification method of mineral structural chemistry. Referring to Professor Friedrich Libau’s classification method, structural chemistry of all silicate minerals containing H+ ion is classified.