In the new era of significantly improved material living conditions, graduate students are reluctant to bear hardships, especially for engineering majors, graduates are not strong enough to choose enterprises and take root in the engineering site; on the other hand, modern enterprises are faced with the challenge of complex technical problems in the engineering site conditions, and urgently need a large number of high-level technical personnel. In view of this time background, Chongqing University takes the resource and environment majors as an example to explore the value-leading education system of engineering postgraduates that serves the needs of complex engineering talents. Conduct questionnaire survey to analyze the reasons why engineering graduate students are unwilling to go to the enterprise level; construct the value leading education system from ideal belief, knowledge, example guidance, engineering practice and innovation training, construct the characteristics of the university and the whole process education system in the College of Resources and Safety of Chongqing University, and achieved good results.