Volume 38,Issue 2,2015 Table of Contents

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  • 1  Combustion characteristics and kinetic analysis of blended coal ofupgraded low rank coal and bituminous coal injected into blast furnace
    XU Runsheng ZHANG Jianliang WANG Guangwei SONG Tengfei WANG Haiyang LIU Siyuan
    2015, 38(2):1-10. DOI: 10.11835/j.issn.1000-582X.2015.02.001
    [Abstract](1552) [HTML](443) [PDF 11.32 M](1150)
    Abstract:
    Thermo-gravimetric analysis is performed to study the combustion performance of upgraded low rank coal,bituminous coal injected into blast furnace and their mixture.It’s studied the relationship between adding quantity of upgraded low rank coal and change rules of blended coal combustion index and their influence on each other.Blended combustion kinetics is analyzed by using the distributed activation energy model (DAEM).The results indicate that the combustion rate of upgraded low rank coal is faster than that of bituminous coal.With the increase of adding quantity of upgraded low rank coal in the blended coal,the ignition temperature gradually decreases,the combustible index and comprehensive combustion index increase,and burning effect gets better.The value of interaction factors K of all blended coals are greater than 1,which suggests that the mutual promotion between upgraded low rank coal and bituminous coal in the combustion process exists.The apparent activation energy of blended coals decrease with the increase of adding quantity of upgraded low rank coal,which indicates the combustion activity of blend coal gradually stronger.
    2  Physical simulation on burden movement in COREX melter gasifier
    HAN Lihao LUO Zhiguo ZOU Zongshu ZHANG Yuzhu
    2015, 38(2):11-16. DOI: 10.11835/j.issn.1000-582X.2015.02.002
    [Abstract](1423) [HTML](315) [PDF 7.02 M](1049)
    Abstract:
    Based on the actual size and operation parameters of COREX melter gasifier and the similarity theory,as caled COREX melter gasifier model is established to study the burden movement.The polyethylene particles and mung bean are used as the packed burden and traceparticles,respectively.The effects of blast volume and discharging rate on flow pattern and trajectory are studied in detail. The results reveal that with the increase of discharging rate,the residence time decreases,the top position of deadman reduces,and the descending of burden movement becomes uneven.With the increase of the blast volume,the upper burden descends more even.Under abnormally discharging condition,the burden movement in meltergasifier would become uneven,which would cause uneven gas distribution in the furnace.The flow behavior in one half of the model appears to be independent of the other half.Particles under deadman descending at the slowest velocity tend to bend to the outlet.Particles above the raceway descend at the fastest velocity,and the blast causes the residence time to be reduced.Particles being close to the furnace wall descend along the wall until they get close to the outlet and then bend.
    3  Analysis of thermal stress in a water pipe of blast furnace copper stave
    LIU Qi CHENG Shusen NIU Jianping LIU Dongdong
    2015, 38(2):17-24. DOI: 10.11835/j.issn.1000-582X.2015.02.003
    [Abstract](1344) [HTML](713) [PDF 8.16 M](1065)
    Abstract:
    To solve the general problem that copper staves experience water pipe failure in blast furnace,the effects of constraints on the thermal stress distribution of copper stave water pipe are investigated by thermal-structural coupling analysis.In this study,a mathematical model of thermal stress of copper stave is established to analyze the thermal deformation and stress distribution of water pipe under subject to different types of constraints.The results show that the thermal stress on the root of water pipe is larger than others as the terminal of water pipe is free or being fixed.But the equivalent stress on the root of water pipe is just 45 MPa as the terminal of water pipe is free,which is lower than the yield strength of pure copper.The equivalent stress on the root of water pipe is about 272 MPa as the terminal of water pipe is being fixed,and exceeds the yield strength of pure copper.The water pipes should be flexible.The maximum equivalent stress is about 600 MPa as the water pipe is subjected to the constraint of shell,which is far beyond the yield strength of pure copper.The maximum displacement is located at the end of water pipe and is about 1.73 mm.Then the diameter of the hole should be 120 mm with taking installation error into consideration.
    4  Reduction roasting and magnetic separation of chromite ore
    QI Jie LIU Chengjun ZHANG Bo JIANG Maofa
    2015, 38(2):25-32. DOI: 10.11835/j.issn.1000-582X.2015.02.004
    [Abstract](1516) [HTML](529) [PDF 10.48 M](1488)
    Abstract:
    Reduction roasting and magnetic separation of chromite ore is investigated,using South African chromite ore as raw materials and Lu’an pulverized coal as reductant.The phase changes in the reduction and magnetic separation process is analyzed systematically by means of SEM-EDS and X ray diffraction.The results show that only iron oxides in the chromite ore are reduced when the temperature is below 1 200 ℃,and chromium oxides are reduced into chromium carbide when the temperature exceeds 1 300 ℃.The spinel structure is transformed and destroyed gradually with the proceeding of reduction reaction.Under the considering experimental conditions,the appropriate temperature for pretreatment is 1 200 ℃,with an iron removal rate of 46%,a chromium yield rate of 80%,and a higher w(Cr2O3)/w(FeO) value of 3.75,the magnetic separation product is mainly iron.This work has great theoretical significance for the development of chromite ore pretreatment process and the comprehensive utilization of low-grade chromite ore.
    5  A model for calculation of theoretical combustion temperature in blast furnace based on fuel calorific value
    ZHANG Yingwei CHENG Shusen
    2015, 38(2):33-38. DOI: 10.11835/j.issn.1000-582X.2015.02.005
    [Abstract](1258) [HTML](787) [PDF 5.30 M](988)
    Abstract:
    In this paper,some modifications on theoretical combustion temperature are made,and a model for calculation of theoretical combustion temperature based on the fuel(coke and coal) calorific value is developed. In the model,the incomplete combustion heat that is released by the fuel can be calculated by difference between the complete combustion heat and the heat loss because of incomplete combustion.Finally,the influence of some factors,such as coal species,coal ratio,oxygen enrichment ratio,on the theoretical combustion temperature are analyzed.
    6  Study on burden pile profile prediction model for COREX-3000 melter gasifier
    LI Haifeng YOU Yang ZHOU Heng LUO Zhiguo ZOU Zongshu
    2015, 38(2):39-44. DOI: 10.11835/j.issn.1000-582X.2015.02.006
    [Abstract](1322) [HTML](314) [PDF 6.40 M](939)
    Abstract:
    The distribution of reducing gas in melter gasifier of COREX-3000 directly influences gas utilization and burden descent.The charging of burden is a main method of regulating gas flow distribution.In order to reveal the burden distribution process,a mathematical model of forecasting the burden pile profile is established based on the impact position,angle of repose and the mass conservation of burden.The impact position of burden is determined by analyzing the material flow trajectory and force during charging process.Based on the mathematical model,an extended burden pile profile prediction software of COREX-3000 melter gasifier is developed by combining mathematic knowledge and computer technology.Using this software,the burden trajectory,the impact position and the burden pile profile under various operations of the coal-gimbal distributor and the DRI-flap distributor can be easily obtained,which can provide reference data for adjusting the charging operation in practice.
    7  Water model study of local stirring and mixing effects of converter
    LI Ziliang CANG Daqiang NI Songming Ouyang Cheng
    2015, 38(2):45-50. DOI: 10.11835/j.issn.1000-582X.2015.02.007
    [Abstract](1264) [HTML](604) [PDF 6.76 M](1059)
    Abstract:
    In order to investigate the local and stirring effect of converters, a converter water model whose prototype is a 55 t converter is built. The method of multi-electrode simultaneous detection is used under different blowing ways. Under pure bottom blowing conditions, the mixing time at the bottom center is relatively short. While, in the condition of top blowing, the weak stirring zone is at the bottom center. In the condition of top-bottom combined blowing, with the increase of lance height, the mixing time of the position of the 4 measuring points in BOF bath first decrease and then increase. And the bottom nozzles layout is obtained when the average mixing time is the shortest. When the lance height is 0.16 m, the mixing effect is better on the upper and lower part of the sidewall and at the center of circulation; when the lance height is 0.20 m, the mixing time at the bottom center is the shortest. The stirring and mixing effect of the symmetrical and the asymmetrical layout of bottom blowing nozzles is compared, and it’s found the asymmetrical and centralized arrangement is more conductive to improve the flow field of the converter and reduce weak stirring zones.
    8  Water modeling on bottom-argon blowing in a 70 t ladle
    WANG Yang LI Jingshe ZHANG Jiangshan GUO Xiaochen
    2015, 38(2):51-57. DOI: 10.11835/j.issn.1000-582X.2015.02.008
    [Abstract](1176) [HTML](500) [PDF 7.52 M](1200)
    Abstract:
    Water modeling is employed to study the bottom-argon blowing in a 70 t LF ladle with a scale of 1∶3. By taking construction features and technological rationality into consideration, nine alternative plugs located at three different radial directions are designed to investigate the effects of argon flow rate, location of the plug, plug number on mixing phenomenon. The results show that the mixing time decreases evidently with increasing argon flow rate within the range of small flow rates. When the flow rate reaches 400 L/min or more, the mixing time becomes to decrease slowly; increasing the number of plug from one to two shows less contribution to the performance of mixing at the same flow rate; and the case reaches the relatively best performance with the plug moves from 0.55R to 0.67R at the original direction.
    9  Penetration behavior of bath induced by top-blown gas jets for steelmaking converter
    LI Mingming LI Qiang ZHANG Wei ZOU Zongshu
    2015, 38(2):58-63. DOI: 10.11835/j.issn.1000-582X.2015.02.009
    [Abstract](1409) [HTML](354) [PDF 6.17 M](1177)
    Abstract:
    The cavity induced by top-blow gas jets impinging on the bath surface is one of most important parameters, which has overwhelming influence on the rate of slag formation and metallurgical performance. Water model experiments are conducted through a 1/10 scaled-down top-blown convertor. Effects of lance height and gas flow rate on penetration behavior are studied, and also the influence mechanism of liquid surface tension on penetration depth is addressed based on the experiments and theory analysis. An energy utilization index (EUI) is defined to reflect how much the impinging kinetic energy of gas jets are transferred into bath for formation of cavity, and an improved model is proposed to predict penetration depth of jets. The results show that penetration depth increases with lowering lance height and increasing gas flow rate, and impact diameter increases with increasing lance height, but is little affected by gas flow rate. Influence of liquid surface tension on penetration depth is enhanced with increasing surface tension and penetration depth. The EUI increases with increasing lance height, and a function relationship of it with lance height is obtained based on the experiments.
    10  Physical simulation of fluid field and structure optimization in two-strand tundish
    LI Guangqiang FU Yong CHEN Xianhong ZHANG Zhan RAO Jiangping YANG Zhizheng
    2015, 38(2):64-71. DOI: 10.11835/j.issn.1000-582X.2015.02.010
    [Abstract](1309) [HTML](306) [PDF 8.40 M](1274)
    Abstract:
    The influence of the structure and location of dam and weir on fluid flow state in a two-strand tundish is studied, and a set of optimal structure, combining with the average residence time calculated from RTD curve, is obtained. The result indicates that the fluid flow state can be changed and the path of the fluid flow can be prolonged as well as the average residence time is improved after using dam and weir. But there are some dead zones after fluid passed through the dam and weir. Combination scheme of No. one dam and weir is better than the others. Its average residence time is 299 s and the volume fraction of dead zone is 31.0%. After the optimization of flowing control parameters in tundish, the best case is that the distance between dam and weir is 290 mm and the distance between weir and the long nozzle is 383 mm. The longest average residence time is 351 s and the minimum volume fraction of dead zone is 19.0% under the above situation. Compared with that of no dam and weir, the average residence time increases by 65 s and the dead zone volume fraction decreases by 15.0%. Based on Newton formula, the calculated results show that the inclusions with diameter larger than 17.5 μm can float up within 351 s under this optimization situation.
    11  Quantitative study on solid slag film’s crystallinity of mould fluxes by using DSC method
    WEN Guanghua WANG Zhe ZHANG Quan HU Quan LU Yifan YANG Changlin
    2015, 38(2):72-79. DOI: 10.11835/j.issn.1000-582X.2015.02.011
    [Abstract](1266) [HTML](372) [PDF 8.30 M](1033)
    Abstract:
    The method to determine the crystallinity of solid slag film is established by analyzing the DSC curve of solid slag film and corresponding quenched slag. The accuracy of the method is investigated by measurements of prepared samples whose crystallinity is given. In addition, the solid slag films of mold slags used to cast medium carbon steel and low carbon steel are obtained by heat flux simulator in laboratory, and the crystallinity of the two kinds of slag film are also measured by DSC method. Experimental results indicates that the crystallinity of solid slag film can be determined by comparing the crystallization enthalpy of solid slag film and corresponding quenched slag during heating process, and the relative error is within 5.03%. For medium carbon steel, the crystalline fraction of solid slag film is 88.6%, while the crystalline fraction of solid slag film corresponding to low carbon steel is 55.0%. The results are consistent with actual structure of solid slag films.
    12  Numerical simulation of columnar dendritic growth with forced convection during the solidification process of Fe-C binary alloy
    LUO Sen WANG Weiling ZHU Miaoyong
    2015, 38(2):80-86. DOI: 10.11835/j.issn.1000-582X.2015.02.012
    [Abstract](1857) [HTML](559) [PDF 7.65 M](970)
    Abstract:
    By coupling the micro-scale cellular automaton method proposed in author’s previous work with the momentum, mass and engery transport models, a multi-scale two-dimensional dendritic growth model (CA-FVM) is developed to investigate the columnar dendritic growth with forced convection. The effects of the forced convection on the columnar dendritic growth of Fe-0.82wt%C binary Fe-based alloy are investigated by the present mathematical model. The numerical results show that the forced convection of the molten melt has great influences on the columnar dendritic growth. The columnar dendrites near the inlet are significantly constrained by the enriched solute which is carried by the forced convection, and grow slowly. But the columnar dendrites far away from the inlet are affected by the forced convection slightly, and grow more fast. Additionally, with the increase of the force convection intensity, the influence of the forced convection on the columnar dendritic growth becomes more significant, and the asymmetric growth of columnar dendrite is intensified.
    13  Water model study on flow optimization of five streams L-type tundish
    MA Guojun CHENG Puhong WANG Chenghui CHENG Changgui
    2015, 38(2):87-92. DOI: 10.11835/j.issn.1000-582X.2015.02.013
    [Abstract](1243) [HTML](354) [PDF 6.00 M](980)
    Abstract:
    In this paper, the water model method is used to optimize the flow behavior of asymmetrical five streams L-type tundish in a steelmaking plant. The results show that the optimization plan is set up with turbulence suppressor T+ vice guide wall D2+ main guide wall with three holes (D1a) which consists of top two holes with 25° inclination and one hole with 30° inclination below. With this plan, the time which the colorants reach to the outlets increases, the difference of response time in all outlets decreases, the peak concentration of the RTD reduces, the existence time of high concentration liquid steel extends, and the ratio of dead zone in each streams reduces.
    14  Precipitation and solid solution of titanium carbonitride inclusions in hypereutectoid tire cord steel
    XUE Zhengliang YU Chenfan QIU Longwu CHEN Wanting ZHANG Jing
    2015, 38(2):93-98. DOI: 10.11835/j.issn.1000-582X.2015.02.014
    [Abstract](1739) [HTML](391) [PDF 5.70 M](1465)
    Abstract:
    The properties of titanium carbonitride (Ti(CxN1-x)) inclusions precipitated during solidification of tire cord steel, as well as thermodynamic conditions of decomposition and solid solution of titanium carbonitride (Ti(CxN1-x)) inclusions in the billet heating process are studied by thermodynamics. The solid solution phenomenon of titanium carbonitride inclusions in the high temperature heating process is studied with lab experiment. The results show 1) The higher the carbon content in tire cord steel, the higher the value of x in titanium carbonitride inclusions; 2) The higher the carbon content in tire cord steel, the earlier the titanium carbonitride inclusions precipitated during solidification process, the lower solidfication front temperature of precipitation of titanium carbonitride inclusions. 3) When heated to 1 087 ℃, the titanium carbonitride inclusions of 82A billet possess the thermodynamic conditions of decomposition and solid solution; 4) When heated to 1 150 ℃ and 1 250 ℃, the content of titanium carbonitride inclusions with size more than 5 μm are decreased by 55% and 70.3% respectively; However the small inclusions with size less than 2 μm continue to decompose, and the content of inclusions with size more than 5 μm increases when the sample is heating at 1 250 ℃ for two hours then furnace cooling to 1 000 ℃.
    15  Bubble distribution of Cr12N high-pressure solidification ingot
    WANG Shuhuan LIU Jimeng ZHAO Dingguo
    2015, 38(2):99-104. DOI: 10.11835/j.issn.1000-582X.2015.02.015
    [Abstract](1305) [HTML](445) [PDF 6.35 M](936)
    Abstract:
    There are a number of bubbles when Cr12N stainless steel is smelted. But its number is smaller and smaller with the increasing of solidification pressure. When the melting pressure is 0.6 MPa and the solidification pressure increases from 1.0 to 1.6 MPa, the average number of bubbles decreases from 46.37 to 9.46 per square millimeter. Bubble number is reduced by 20.4%. The number of bubbles whose diameters are greater than 20 μm is reduced to 17.4%, while the number of bubbles whose diameters are less than 5μm increases by 37.7%. With 0.3 MPa melting pressure and 1.6 MPa solidification pressure, the average bubble size content near the lower surface is 23.9% of that near the upper surface. Average bubble size content at the edge is 25.9% of that at the center. According to the actual nitrogen content in steel ingot calculated by the established mathematical model, no bubbles of high nitrogen steel ingot may be obtained when melting pressure is 0.6 MPa and solidification pressure increases to 1.8 MPa.
    16  Effect of Mg and Zr addition on the continuous cooling transformation of the FH40 ship-building steel
    LI Xiaobing MIN Yi WANG Bo JIANG Maofa
    2015, 38(2):105-110. DOI: 10.11835/j.issn.1000-582X.2015.02.016
    [Abstract](1446) [HTML](396) [PDF 8.96 M](1057)
    Abstract:
    The FH40 ship plates containing different Mg, Zr contents are refined with vacuum induction furnace, and the relationship between magnesium and zirconium addition and the decomposition of austenite during continuous cooling rate from 0.1 ℃/s to 30 ℃/s is systematically investigated by a Gleeble-3800 thermal simulator. Continuous cooled microstructure is observed by means of optical microscope. Dilatometric experiments and metallographic observations show that, Mg, Zr and Mg-Zr addition can affect the starting temperatures of the γ-α phase transformation and the pearlite transformation. Mg and Mg-Zr addition suppresses the proeutectoid ferrite transformation and promotes the bainite transformation. The matrix can be dominated as bainite at cooling rate from 5 ℃/s to 30 ℃/s for the Mg-containing steels. It is obviously shown that the addition of zirconium has a significant effect in promoting the nucleation of ferrites. However, the bainite transformation is not well developed, but an evident suppression of the transformation is emerged for the single Zr addition steel. The above studies can provide theoretical foundations for the application of magnesium and zirconium in steel.
    17  The precipitation behaviors of thesecond phase particles and hot rolled texture in the low temperature grain-oriented silicon steel
    ZHU Chengyi CHEN Xianhong LI Guangqiang FU Yong JIANG Yulong
    2015, 38(2):111-117. DOI: 10.11835/j.issn.1000-582X.2015.02.017
    [Abstract](1308) [HTML](324) [PDF 7.52 M](1351)
    Abstract:
    The precipitation behaviors of the second phase particles and their textures in the low temperature grain-oriented silicon steel are studied under different processes. The results show that not only the dispersed nanoscale spherical or ellipsoidal MnS and Cu2S precipitations are observed in the hot rolled slabs, but also SiO2, AlN and Si3N4 which are similar to MnS and Cu2S in the morphology and complex compounds that are composed by them together are observed. In the sample, precipitations at the micron scale are mainly composed by SiO2, MnS, Cu2S and AlN, and precipitations at the nanoscale are mainly composed by AlN, Si3N4, MnS and Cu2S. The number of precipitates whose size is from 0.01 μm to 0.2 μm is the largest in the hot rolled slabs, which accounts for about 90%. Compared with the conventional hot rolling slabs, the area density of the inclusions in the CSP samples is smaller, but the average size in the range of greater than 1 μm of that is larger. It will make the secondary recrystallization incomplete during the annealing process, and also it can influence the magnetic property of the products. The distribution of texture which is perpendicular to the rolling direction on cross section in the hot rolled slabs is very different. The texture of the CSP samples is relatively uniform, which is harmful to develop complete secondary recrystallization texture during the subsequent treatment process to obtain good magnetic properties.
    18  Effects of flue gas recirculation on combustion characteristic in flat flame gas stove of HTAC
    CHEN Weipeng ZHANG Huan XIE Zhihui ZHAO Zengwu LI Baowei WU Wenfei
    2015, 38(2):118-122. DOI: 10.11835/j.issn.1000-582X.2015.02.018
    [Abstract](1521) [HTML](456) [PDF 4.79 M](1222)
    Abstract:
    The flame temperature is higher and thermal NOx generation is bigger when flat flame combustion and the regenerative combustion technology are used together. Flue gas recirculation is one of the effective ways to reduce thermal NOx generation in the process of HTAC. Flame features, furnace top temperature distribution and generating characteristic of NO with and without flue gas recirculation are studied by means of flat flame gas stove of HTAC and analytical instruments for flue gas and thermocouple. The results show that flue gas recirculation make dark area of flat flame smaller, burning area expand, flame temperature distribution more uniform and NO concentration in flue gas obviously decrease. Peak temperature decreases 9 ℃,valley value of temperature increases 37 ℃, and the maximum NO concentration reduces 20%.
    19  Analysis on transfer and enrichment of metal elements during reduction roasting of vanadium tailings
    YU Xiong SUN Lifeng WANG Hesong ZHUO Yukun LUO Peng
    2015, 38(2):123-129. DOI: 10.11835/j.issn.1000-582X.2015.02.019
    [Abstract](1355) [HTML](379) [PDF 7.34 M](1120)
    Abstract:
    Based on the carbon thermodynamic analysis, experiments of pellet reduction-roasting of vanadium tailings are conducted. With phase and component analysis, carbon thermal reduction process of metal oxide in vanadium tailings is systematically studied. The results indicate that under different reduction temperatures, reduction process of iron, chromium, vanadium, manganese and titanium exhibit different characteristics and transfer rules.
    20  Thermodynamics analysis on the carbochlorination of flyash
    LI Yong DUAN Dongping LIU Yan
    2015, 38(2):130-137. DOI: 10.11835/j.issn.1000-582X.2015.02.020
    [Abstract](1362) [HTML](307) [PDF 8.81 M](1320)
    Abstract:
    Because of the high altitude of Qinghai, its air pressure is 0.77 atm which is lower than the atmospheric pressure. Therefore, an analysis is done for carbochlorination reaction of flyash for the extraction of aluminum in such an environment. The phase diagrams and predominance area diagram on chlorides are calculated and drawn and the equilibrium compositions of complex system composed of multi-components are simulated by Factsage software. Results show that, carbochlorination reaction converts Al2O3 and SiO2 which can not directly react with chlorine gas originally to chloride completely, and this demonstrates the thermodynamics feasibility of carbochlorination process. The ratio of FeCl3(Fe2Cl6) to FeCl2 changes with the amount of carbon and chlorine gas. The catalysts like Na2CO3, CaCO3 and B2O3 have some side effects in the aspect of thermodynamics such as consuming chlorine gas and carbon. The volatility of AlCl3(Al2Cl6) is affected by other chlorides. Compared with the normal pressure region, there are advantages and disadvantages to carbochlorination reaction under the pressure below the normal. The work provides thermodynamic data for the process.
    21  Vanadium extraction from molten vanadium slag with high contents of Ca and P by direct oxidation and adding Na2CO3 and water leaching method
    LI Hong WANG Yannan SONG Wenchen
    2015, 38(2):138-142. DOI: 10.11835/j.issn.1000-582X.2015.02.021
    [Abstract](1531) [HTML](314) [PDF 5.35 M](1083)
    Abstract:
    The mineral phases of the clinker obtaining after oxidizing vanadium slag with high contents of Ca and P are analyzed by X-ray diffraction (XRD), and the experimental parameters of vanadium extraction are also investigated in this paper. The results show that V exists in the form of Na4V2O7, Na3VO4, Na1.33V2O5 and NaCaVO4 when the amount of added Na2CO3 is relatively small (35%). But, with the added Na2CO3 amount increasing, Na4V2O7 and NaCaVO4 react with Na2CO3, then change into Na3VO4. P in the clinker exists in the form of Na3PO4. The leaching rate of vanadium can reach above 90% under the conditions: added Na2CO3 amount of 40%, liquid to solid ratio of 5∶1 mL/g, leaching temperature of 90℃, leaching time of 4 min, stirring rate of 150 r/min. Therefore, the method of extracting vanadium from molten vanadium slag with high contents of Ca and P by direct oxidation and adding Na2CO3 and water leaching is feasible.

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